Both the acetamido (-NHCOCH3) and bromo (-Br) substituents are ortho, para directors. Even though the acetamido group is much la
rger than the bromo group, the -Cl is still introduced next to the acetamido group in spite of the greater steric hinderance at this site. Why?
1 answer:
Answer:
Explanation has been given below
Explanation:
- Attachment of -Cl group at ortho position to acetamido group can be explained in terms of hydrogen bonding formation.
- A hydrogen bonding can be formed between proton attached with N atom in acetamido group and Cl atom at ortho position. This leads to a formation of a stable 5-membered ring structure.
- Hence ortho substitution by Cl is favorable process.
- There is no hydrogen bonding possible between Br and Cl atom in ortho position. Therefore Cl prefers para position to avoid steric hindrance.
- Structure of hydrogen bonded structure has been shown below.
You might be interested in
Answer:
Atom is the smallest particle of matter.
Elements are made up of same atoms.
Atom consist of electron, proton and neutron.
Explanation:
Atom was first discovered by John Dalton.
word "Atom" came from Greek word, that means something that could not split. he explained that atom is indivisible particle.
In the end of 18th century J.J. Thomson put forward a new concept of atom. he said that atom have negative charged particles called electrons but overall atom is neutral.
In 1909 Rutherford with his students discovered positive charged particles and nucleus and said that it is in the center of atom.
He explain a model of atom and said that electrons revolve around a hard core in the center called nucleus.
In 1913 Niels Bohr explains the atomic spectra and put forward the concept of shells and sub-shells.
So overall Structure of an Atom is
- consist of Neutrons in nucleus
- +ve charged protons in nucleus
- A -vely charged electrons revolving around the nucleus
- the electron revolve in shells i.e. K, L, M, and N
- Each shell divide in sub-Shell such as s, p,d and f.
Atom has a specific atomic mass and atomic number
Atomic number = number of protons or electron
Atomic mass = number of protons + number of neutrons in nucleus.
FeOH2 = 73.8602753 g/mol
FOLLOW ME FOR CLEARING YOUR NEXT DOUBT
Given
3000 L of gas at 39°C and 99 kPa to 45.5 kPa and 16°C,
Required
the new volume
Solution
Combined with Boyle's law and Gay Lussac's law
T₁ = 39 + 273 = 312
T₂ = 16 + 273 = 289
Input the value :
V₂ = (P₁V₁.T₂)/(P₂.T₁)
V₂ = (99 x 3000 x 289)/(45.5 x 312)
or we can write it as:
V₂ = 3000 L x (289/312) x (99/45.5)