Answer:
- About 18 g of NH₄Cl will precipitate.
Explanation:
The <em>table G</em> is the graph of the solubility curves for several solutes which is attached.
The second picture identifies the solubilities for the NH₄Cl at 50ºC and 10ºC.
The solubility of NH₄Cl at 50ºC is about 52 g/ 100 g of water.
The solubility of NH₄Cl at 10ºC is about 34 g / 100 g of water.
Then, at 50ºC 100 g of water saturated with NH₄Cl contains about 52 g of NH₄Cl and 100 g of water saturated with NH₄Cl contains 34 g of NH₄Cl.
The difference, 52g - 34 g of NH₄Cl shall precipitate:
52 g - 34 g = 18g ← answer
Formic acid is the simplest carboxylic acid with a structure of HCOOH and has a pka of 3.75. The pka refers to the acidity of the molecule, which in this example refers to the molecules ability to give up the proton of the O-H. A decrease in the pka value corresponds to an increase in acidity, or an increase in the ability to give up a proton. When an acid gives up a proton, the remaining anionic species (in this case HCOO-) is called the conjugate base, and an increase in the stability of the conjugate base corresponds to an increase in acidity.
The pka of a carboxylic can be affected greatly by the presence of various functional groups within its structure. An example of an inductive effect changing the pka can be shown with trichloroacetic acid, Cl3CCOOH. This molecule has a pka of 0.7. The decrease in pka relative to formic acid is due to the presence of the Cl3C- group, and more specifically the presence of the chlorine atoms. The electronegative chlorine atoms are able to withdraw the electron density away from the oxygen atoms and towards themselves, thus helping to stabilize the negative charge and stabilize the conjugate base. This results in an increase in acidity and decrease in pka.
The same Cl3CCOOH example can be used to explain how dipoles can effect the acidity of carboxylic acids. Compared to standard acetic acid, H3CCOOH with a pka of 4.76, trichloroacetic acid is much more acidic. The difference between these structures is the presence of C-Cl bonds in place of C-H bonds. A C-Cl bond is much more polar than a C-H bond, due the large electronegativity of the chlorine atom. This results in a carbon with a partial positive charge and a chlorine with a partial negative charge. In the conjugate base of the acid, where the molecule has a negative charge localized on the oxygen atoms, the dipole moment of the C-Cl bond is oriented such that the partial positive charge is on the carbon that is adjacent to the oxygen atoms containing the negative charge. Therefore, the electrostatic attraction between the positive end of the C-Cl dipole and the negative charge of the anionic oxygen helps to stabilize the entire species. This level of stabilization is not present in acetic acid where there are C-H bonds instead of C-Cl bonds since the C-H bonds do not have a large dipole moment.
To understand how resonance can affect the pka of a species, we can simply compare the pka of a simple alcohol such as methanol, CH3OH, and formic acid, HCOOH. The pka of methanol is 16, suggesting that is is a very weak acid. Once methanol gives up that proton to become the conjugate base CH3O-, the charge cannot be stabilized in any way and is simply localized on the oxygen atom. However, with a carboxylic acid, the conjugate base, HCOO-, can stabilize the negative charge. The lone pair electrons containing the charge on the oxygen atom are able to migrate to the other oxygen atom of the carboxylic acid. The negative charge can now be shared between the two electronegative oxygen atoms, thus stabilizing the charge and decreasing the pka.
Answer;
A) Stage 1: Chlorophyll captures light energy. Stage 2: Light energy is converted to chemical energy.
Explanation;
-Photosynthesis is the process by which green plants use energy from the sun, water and carbon dioxide to make organic compounds such as simple sugars together with release of oxygen.
-The process occurs in tow stages; light-dependent stage and light independent stage. During light dependent stage, chlorophyll absorbs sunlight and uses it to split water molecules into hydrogen ions and oxygen atoms. In the light independent stage carbon (iv) dioxide is fixed and the result is organic compound; the light energy is converted to chemical energy.
Answer : The final number of moles of gas that withdrawn from the tank to lower the pressure of the gas must be, 0.301 mol.
Explanation :
As we know that:
At constant volume and temperature of gas, the pressure will be directly proportional to the number of moles of gas.
The relation between pressure and number of moles of gas will be:
where,
= initial pressure of gas = 24.5 atm
= final pressure of gas = 5.30 atm
= initial number of moles of gas = 1.40 moles
= final number of moles of gas = ?
Now put all the given values in the above expression, we get:
Therefore, the final number of moles of gas that withdrawn from the tank to lower the pressure of the gas must be, 0.301 mol.
Answer:
o
Explanation:
it is not a gas because the particles do not move freely it may be a liquid or a solid partly and mostly liquidized.
