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Georgia [21]
3 years ago
11

The p K b pKb values for the dibasic base B B are p K b1 = 2.10 pKb1=2.10 and p K b2 = 7.84 . pKb2=7.84. Calculate the pH at eac

h of the points in the titration of 50.0 mL of a 0.50 M B ( aq ) 0.50 M B(aq) solution with 0.50 M HCl ( aq ) .
Chemistry
1 answer:
Karo-lina-s [1.5K]3 years ago
4 0

WOW WHAT?! IS THIS COLLAGE?! cause then i dont think i wanna go to collage....

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A mixture containing 20 mole % butane, 35 mole % pentane and rest
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Answer:

2.5 % butane, 42.2 % pentane and 55.3 % hexane

Explanation:

Hello,

In this case, the mass balance for each substance is given by:

Butane:z_bF=y_bD+x_bB\\\\Pentane: z_pF=y_pD+x_pB\\\\Hexane: z_hF=y_hD+x_hB

Whereas y accounts for the fractions at the outlet distillate and x for the fractions at the outlet bottoms. Moreover, with the 90 % recovery of butane, we can write:

0.9=\frac{y_bD}{z_bF}

So we can compute the product of the molar fraction of butane at the distillate by total distillate flow by assuming a 100-mol feed:

y_bD=0.9*z_bF=0.9*0.2*100mol=18mol

The total distillate flow:

y_bD=18mol\\\\D=\frac{18mol}{0.95} =18.95mol

And the total bottoms flow:

F=D+B\\\\B=F-D=100mol-18.95mol=81.05mol

Next, by using the mass balance of butane, we compute the molar fraction of butane at the bottoms:

x_b=\frac{z_bF-y_bD}{B} =\frac{0.2*100mol-18mol}{81.05} =0.025

Then, the molar fraction of pentane and hexane:

x_p=\frac{z_pF-y_pD}{B} =\frac{0.35*100mol-0.04*18.95mol}{81.05} =0.422

x_h=\frac{z_hF-y_hD}{B} =\frac{(1-0.2-0.35)*100mol-(1-0.95-0.04)*18.95mol}{81.05} =0.553

Therefore, the molar composition of the bottom product is 2.5 % butane, 42.2 % pentane and 55.3 % hexane.

NOTE: notice the result is independent of the value of the assumed feed, it means that no matter the basis, the compositions will be the same for the same recovery of butane at the feed, only the flows will change.

Regards.

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