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Dmitry [639]
3 years ago
9

If there are 40 mol of NBr3 and 48 mol of NaOH, what is the excess reactant?

Chemistry
2 answers:
Nata [24]3 years ago
6 0

Answer:

The correct answer is option B.

Explanation:

3NaOH+2NBr_3\rightarrow 3HOBr+3NaBr+N_2

Moles of NBr_3 = 40 mol

Moles of NaOH = 48 mol

According to reaction, 3 moles of NaOH reacts with 2 moles NBr_3

Then ,48 moles of NaOH will reacts with:

\frac{2}{3}\times 48 mol=32 mol of NBr_3

Then ,40 moles of NaBr_3 will reacts with:

\frac{3}{2}\times 40 mol=60 mol of NaOH

As we can see that 48 moles of sodium will completey react with 32 moles of nitrogen tribromide.

Moles left after reaction = 40 mol - 32 mol = 8 mol

Hence, the NBr_3 is an excessive reagent.

Triss [41]3 years ago
5 0

Answer : The correct option is (B) NBr_3

Solution : Given,

Moles of NBr_3 = 40 mol

Moles of NaOH = 48 mol

Now we have to calculate the limiting and excess reagent.

The balanced chemical reaction is,

2NBr_3+3NaOH\rightarrow N_2+3NaBr+3HOBr

From the balanced reaction we conclude that

As, 3 mole of NaOH react with 2 mole of NBr_3

So, 48 moles of NaOH react with \frac{48}{3}\times 2=32 moles of NBr_3

From this we conclude that, NBr_3 is an excess reagent because the given moles are greater than the required moles and NaOH is a limiting reagent and it limits the formation of product.

Excess moles of NBr_3 = 40 - 32 = 8 moles

Hence, the correct option is (B) NBr_3

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A student wishes to calculate the experimental value of Ksp for AgI. S/he follows the procedure in Part 3 and finds Ecell to be
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Answer:

a)    [Ag+]dilute = 6.363  × 10⁻¹⁶ M  

b)    1.273 × 10⁻¹⁶

c)    2.629×10⁻¹⁹ M Thus; the value for  [Ag+ ]dilute will be too low

Explanation:

In an Ag | Ag+ concentration cell ,

The  anode reaction can be written as :

Ag ----> Ag+(dilute) + e-    &:

The  cathode reaction can be written as:

Ag+(concentrated) + e- ----> Ag

The  Overall Reaction : is

Ag+(concentrated) -----> Ag+(dilute)

However, the Standard Reduction potential of cell = E°cell = 0

( since both cathode and anode have same Ag+║Ag )

Also , given that the theoretical slope is - 0.0591 V

Therefore; the reduction potential of cell ; i.e

Ecell = E°cell - 0.0591 V × log ( [Ag+]dilute / [Ag+]concentrated )

0.839 V = 0 - 0.0591 V × log ( [Ag+]dilute / ( 1.0 × 10⁻¹ M ) )  

log ( [Ag+]dilute / ( 1.0 × 10⁻¹ M ) ) = - 14.1963  

[Ag+]dilute = \mathbf{10^{-14.1963} } × 1.0 × 10⁻¹ M

[Ag+]dilute = 6.363  × 10⁻¹⁶ M  

b)

AgI ----> Ag + (dilute) + I⁻

So , Solubility product = Ksp = [Ag⁺]dilute × [I⁻]  

= 6.363 × 10⁻¹⁶ M × 0.20 M  

= 1.273 × 10⁻¹⁶

c) If s/he mistakenly uses 1.039 V as Ecell; then the value for [Ag+]dilute will be :

Ecell = E°cell - 0.0591 V × log ( [Ag+]dilute / [Ag+]concentrated )

1.039 V = 0 - 0.0591 V × log ( [Ag+]dilute / ( 1.0 × 10⁻¹ M ) )  

log ( [Ag+]dilute / ( 1.0 × 10⁻¹ M ) ) = - 17.5804  

[Ag+]dilute = \mathbf{10^{-17.5804} } × 1.0 × 10⁻¹ M

[Ag+]dilute = 2.629×10⁻¹⁹ M

Thus, the value for  [Ag+ ]dilute will be too low

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Answer:

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The formula for the calculation of moles is shown below:

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4 moles of aluminum react with 3 moles of oxygen gas

1 mole of aluminum react with \frac{3}{4} moles of oxygen gas

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Moles of oxygen gas = 1.5288 moles

At STP,  

Pressure = 1 atm  

Temperature = 273.15 K

Using ideal gas equation as:

PV=nRT

where,

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R is Gas constant having value = 0.0821 L.atm/K.mol

Applying the equation as:

1 atm × V = 1.5288 mol × 0.0821 L.atm/K.mol × 273.15 K

⇒V = 34.28 L ( 1.5*22.4 L)

7 0
3 years ago
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