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boyakko [2]
3 years ago
8

The combustion of propane may be described by the chemical equation C 3 H 8 ( g ) + 5 O 2 ( g ) ⟶ 3 CO 2 ( g ) + 4 H 2 O ( g ) C

3H8(g)+5O2(g)⟶3CO2(g)+4H2O(g) How many grams of O 2 ( g ) O2(g) are needed to completely burn 19.7 g C 3 H 8 ( g ) ?
Chemistry
1 answer:
Kipish [7]3 years ago
7 0

Answer: 72 grams of O_2(g) are needed to completely burn 19.7 g C_3H_8(g)

Explanation:

According to avogadro's law, 1 mole of every substance weighs equal to molecular mass and contains avogadro's number 6.023\times 10^{23} of particles.

To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}

Putting in the values we get:

\text{Number of moles}=\frac{19.7g}{44g/mol}=0.45moles

C_3H_8(g)+5O_2(g)\rightarrow 3CO_2(g)+4H_2O(g)

According to stoichiometry:

1 mole of C_3H_8 requires 5 moles of oxygen

0.45 moles of C_3H_8 require= \frac{5}{1}\times 0.45=2.25 moles of oxygen

Mass of O_2=moles\times {\text {Molar mass}}=2.25\times 32=72g

72 grams of O_2(g) are needed to completely burn 19.7 g C_3H_8(g)

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Explanation:

The reaction order is the relationship between the concentration of species and the rate of the reaction. The rate law is as follows:

r = k [A]^{x} [B]^{y}

where:

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The concentration time equation gives the concentration of reactants and products as a function of time. To obtain this equation we have to integrate de velocity law:

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For the kinetics of zero-order, the rate is apparently independent of the reactant concentration.

<em>Rate Law:                                    rate = k</em>

<em>Concentration-time Equation:   [A]=[A]o - kt</em>

where

  • k: rate constant [M/s]
  • [A]: concentration in the time <em>t</em> [M]
  • [A]o: initial concentration [M]
  • t: elapsed reaction time [s]

For first-order kinetics, we have:

<em>Rate Law:                                        rate= k[A]</em>

<em>Concentration -Time Equation:      ln[A]=ln[A]o - kt</em>

where:

  • K: rate constant [1/s]
  • ln[A]: natural logarithm of the concentration in the time <em>t </em>[M]
  • ln[A]o: natural logarithm of the initial concentration [M]
  • t: elapsed reaction time [s]

To solve the problem, wee have the following data:

[A]o = 100 mg/L

[A] = 5 mg/L

t = 1 hour = 60 s

As we don't know the molar mass of the compound A, we can't convert the used concentration unit (mg/L) to molar concentration (M). So we'll solve the problem using mg/L as the concentration unit.

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we use:                        [A]=[A]o - Kt

we replace the data:   5 = 100 - K (60)

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First-order kinetics

we use:                                  ln[A]=ln[A]o - Kt

we replace the data:               ln(5)  = ln(100) - K (60)

we clear K:                                   K = [ln(100) - ln(5)] /60 (s)  = 0,05 [1/s]

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