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andrezito [222]
3 years ago
14

Cyclopropane thermally decomposes by a first‑order reaction to form propene. If the rate constant is 9.6 s − 1 , what is the hal

f‑life of the reaction? half‑life: s How long does it take for the concentration to reach 0.50 of its initial value? amount of time: s
Chemistry
1 answer:
DiKsa [7]3 years ago
7 0

Answer:

Cyclopropane will take 0.072 secs to reach 0.50 of its initial concentration.

Explanation:

For a first order kinetics half- life of the reaction can be calculated by the formula,

half-life = \frac{0.693}{k}

Half-life of cyclopropane will be,

t_{1/2}= \frac{0.693}{9.6s^{-1} }

t_{1/2} =0.072 sec

Since, 0.50 means half of the initial concentration, which itself depicts the half- life of the cyclopropane. Therefore it, will take 0.072 secs to reach 0.50 of its initial concentration i.e it will reduce to half of initial concentration in 0.072 secs when it thermally decomposes.

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The questions are attached​
Sladkaya [172]

Answer:

Explanation:

a) Balanced chemical equation:

C₃H₈ + 5O₂      →        3CO₂ + 4H₂O

b) Mass of oxygen gas needed = ?

Mass of propane = 25 g

Solution:

Number of moles of propane = mass/molar mass

Number of moles = 25 g/  44.1 g/mol

Number of moles = 0.57 mol

now we will compare the moles of oxygen and propane:

                            C₃H₈        :          O₂        

                                1           :            5

                             0.57        :         5/1×0.57 =  2.85 mol

Mass of oxygen:

Mass = number of moles × molar mass

Mass = 2.85 mol × 32 g/mol

Mass = 91.2 g    

c) water vapors produced = ?

Mass of propane = 25 g

Solution:

Number of moles of propane = mass/molar mass

Number of moles = 25 g/  44.1 g/mol

Number of moles = 0.57 mol

now we will compare the moles of water and propane:

                            C₃H₈        :          H₂O        

                                1           :            4

                             0.57        :         4/1×0.57 =  2.28 mol

Mass of water vapors:

Mass = moles × molar mass

Mass = 2.28 mol × 18 g/mol

Mass = 41.0 g

d)

mass of water vapors produced = 1.5 kg (1500 g)

Mass of propane reacted = ?

Solution:

Number of moles of water vapors:

Number of moles = mass/molar mass

Number of moles = 1500 g/ 18 g/mol

Number of moles = 83.33 mol

now we will compare the moles of water and propane.

         

                            H₂O          :            C₃H₈    

                               4            :              1

                             83.3         :         1/4×83.3 =  20.8 mol

Mass of propane:

Mass = number of moles ×molar mass

Mass = 20.8 mol × 44.1 g/mol

Mass = 917 g

3 0
3 years ago
An atom of lead has a radius of and the average orbital speed of the electrons in it is about . Calculate the least possible unc
victus00 [196]

The question is incomplete. Here is the complete question.

An atom of lead has a radius of 154 pm and the average orbitalspeed of the electron in it is about 1.8x10^{8} m/s. Calculate the least possible uncertainty in a measurement of the speed of an electron in an atom of lead. Write your answer as a percentage of the average speed, and round it to significant 2 digits.

Answer: v% = 0.21 m/s

Explanation: To calculate the uncertainty, use <u>Heisenberg's Uncertainty Principle</u>, which states that:  ΔpΔx≥\frac{h}{4\pi }

where h is <u>Planck's constant</u> and it is equal to 6.626.10^{-34}m²kg/s.

Since p (momentum) is p = m.v:

mΔv.Δx ≥ \frac{h}{4\pi }

Δv = \frac{h}{4\pi.x.m }

Given that: r = x = 1.54.10^{-10}m and mass of an electron is m=9.1.10^{-31}kg

Δv = \frac{6.626.10^{-34} }{4.3.14.1.54.10^{-10}.9.1.10^{-31}}

Δv = 0.0376.10^{7}

As percentage of average speed:

Δv.\frac{1}{v}.100% = \frac{0.0376.10^{7} }{1.8.10^{8} }.10² = 0.021.10 = 0.21%

The least possible uncertainty in a speed of an electron is 0.21%.

5 0
4 years ago
The
goldfiish [28.3K]

Answer: …

Explanation:

5 0
2 years ago
Which of the following elements has the lowest electronegativity?
Bess [88]

Answer:

A. Barium

Explanation:

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8 0
4 years ago
Read 2 more answers
Draw both the chair and boat conformation of 1,4-dimethylcyclohexane with the methyl groups as cis and trans for both conformati
andrezito [222]

Answer:

Boat conformation cis 1,4-dimethyl cyclohexane has the highest energy.

Explanation:

From the conformations, the boat conformation cis 1,4-dimethyl cyclohexane is least stable due to the fact that two methyl groups are located in opposite direction to each other, this leads to the production of  a higher strain. Similarly, Chair conformations appear more stable than boat conformation. Hence, energy is inversely proportional to stability. As a result of the aforementioned, boat conformation cis 1,4-dimethyl cyclohexane has the highest energy.

8 0
3 years ago
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