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aniked [119]
3 years ago
13

Which of the following two combinations of reactants is more appropriate for the preparation of p-nitrophenyl phenyl ether? Fluo

robenzene and sodium p-nitrophenoxide, or p-fluoronitrobenzene and sodium phenoxide.

Chemistry
1 answer:
VladimirAG [237]3 years ago
5 0

Answer:

p-fluoronitrobenzene and sodium phenoxide is more appropriate

Explanation:

An ipso substitution is required to form p-nitrophenyl phenyl ether.

For this ipso substitution, an alkoxide anion needs to attack as a nucleophile at the carbon atom attached to fluorine atom and thereby substitute that F atom.

p-nitrophenoxide is an weak nucleophile as compared to phenoxide due to presence of electron withdrawing resonating effect of nitro group at para position.

p-fluoronitrobenzene is a good choice for nucleophilic attack by alkoxide anion as compared to fluorobenzene due to higher positive charge density at carbon atom directly attached to F atom. Higher positive charge density arises due to presence of electron withdrawing resonating effect og nitro group at para position.

So, p-fluoronitrobenzene and sodium phenoxide is more appropriate

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Boron (B) has two isotopes, boron-10 and boron-11. The atomic weight of boron is ?
suter [353]

Answer:

Approximately 10,5

Explanation:

The question is not really very specific, because it would need the percentages of those isotopes in the nature. As they are not shown, it should be the median of those two numbers.

atomic weight ≈ \frac{10+11}{2} = 10,5

If you check a periodic table, you'll see it's actually 10,8, but that's because of the thing I told you at first (percentages missing).

Hope I could help.

8 0
3 years ago
"How much NH4Cl, when present in 2.00 liters of 0.200 M ammonia, will give a solution with pH = 8.20? For NH3, Kb = 1.8 x 10-5"
Andru [333]

Answer:

245.66g of NH₄Cl is the mass we need to add to obtain the desire pH

Explanation:

The mixture of NH3/NH4Cl produce a buffer. We can find the pH of a buffer using H-H equation:

pH = pKa + log [A⁻] / [HA]

<em>Where [A⁻] is the molar concentration of the base, NH₃, and [HA] molar concentration of the acid, NH₄⁺. This molar concentration can be taken as the moles of each chemical</em>

<em />

First, we need to find pKa of NH₃ using Kb. Then, the moles of NH₃ and finally replace these values in H-H equation to solve moles of NH₄Cl we need to obtain the desire pH.

  • <em>pKa NH₃/NH₄⁺</em>

pKb = - log Kb

pKb = -log 1.8x10⁻⁵ = <em>4.74</em>

pKa = 14 - pKb

pKa = 14 - 4.74

pKa = 9.26

  • <em>Moles NH₃</em>

<em>2.00L ₓ (0.200mol NH₃ / L) = 0.400 moles NH₃</em>

  • <em>H-H equation:</em>

pH = pKa + log [NH₃] / [NH₄Cl]

8.20 = 9.26 + log [0.400 moles] / [NH₄Cl]

-1.06 =  log [0.400 moles] / [NH₄Cl]

0.0087 =  [0.400 moles] / [NH₄Cl]

[NH₄Cl] = 0.400 moles / 0.0087

[NH₄Cl] = 4.59 moles of NH₄Cl we need to add to original solution to obtain a pH of 8.20. In grams (Using molar mass NH₄Cl=53.491g/mol):

4.59 moles NH₄Cl ₓ (53.491g / mol) =

<h3>245.66g of NH₄Cl is the mass we need to add to obtain the desire pH</h3>

<em />

3 0
4 years ago
Choose all the answers that apply.
Stolb23 [73]

Answer:

the first statement

Explanation:

hope this helps

please like and Mark as brainliest

6 0
3 years ago
Scientists can tell recycling reduces atmospheric emissions by knowing which of the following? o it takes more Btu to manufactur
Dmitriy789 [7]

Answer:

According to the Environmental Paper Network's Paper Calculator, it takes about 32 million BTUs of energy to produce 1 ton of virgin paper fiber. To produce 1 ton of recycled paper, it takes about 22 million BTUs.

so the answer could be it takes less Btu to manufacture recycled products than new ones

7 0
3 years ago
Describe how hydrogen and oxygen form water
Gwar [14]

Answer:

The  hydrogen molecules combine with the oxygen molecules, 2 hydrogen molecules, and 1 oxygen molecules is the amount needed to make one water atom or molecule, whatever you want to call it.

7 0
3 years ago
Read 2 more answers
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