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Answer:
Part a: The rate of the equation for 1st order reaction is given as ![Rate=k[H_2O_2]](https://tex.z-dn.net/?f=Rate%3Dk%5BH_2O_2%5D)
Part b: The integrated Rate Law is given as ![[H_2O_2]=[H_2O_2]_0 e^{-kt}](https://tex.z-dn.net/?f=%5BH_2O_2%5D%3D%5BH_2O_2%5D_0%20e%5E%7B-kt%7D)
Part c: The value of rate constant is 
Part d: Concentration after 4000 s is 0.043 M.
Explanation:
By plotting the relation between the natural log of concentration of
, the graph forms a straight line as indicated in the figure attached. This indicates that the reaction is of 1st order.
Part a
Rate Law
The rate of the equation for 1st order reaction is given as
![Rate=k[H_2O_2]](https://tex.z-dn.net/?f=Rate%3Dk%5BH_2O_2%5D)
Part b
Integrated Rate Law
The integrated Rate Law is given as
![[H_2O_2]=[H_2O_2]_0 e^{-kt}](https://tex.z-dn.net/?f=%5BH_2O_2%5D%3D%5BH_2O_2%5D_0%20e%5E%7B-kt%7D)
Part c
Value of the Rate Constant
Value of the rate constant is given by using the relation between 1st two observations i.e.
t1=0, M1=1.00
t2=120 s , M2=0.91
So k is calculated as

The value of rate constant is 
Part d
Concentration after 4000 s is given as

Concentration after 4000 s is 0.043 M.
Milli<span>- (symbol m) is a unit </span>prefix<span> in the metric system denoting a factor of one thousandth (10</span>−3<span>). Proposed in 1793 and adopted in 1795, </span>the prefix<span> comes from the Latin mille, </span>meaning<span> "one thousand" (the Latin plural is milia).</span>
1.39 g HCl
Explanation:
The balanced chemical equation for this reaction is given by
Zn(<em>s</em>) + 2HCl(<em>aq</em>) ---> ZnCl2(<em>aq</em>) + H2(<em>g</em>)
Convert the # of grams of Zn to moles:
1.25 g Zn × (1 mol Zn/65.38 g Zn) = 0.0191 mol Zn
Use the molar ratio to find the # of moles of HCl needed to react completely with the given amount of Zn:
0.0191 mol Zn × (2 mol HCl/1 mol Zn) = 0.0382 mol HCl
Convert this amount to grams:
0.0382 mol HCl × (36.458 g HCl/1 mol HCl) = 1.39 g HCl