Purification of chromium can be achieved by electrorefining chromium from an impure chromium anode onto a pure chromium cathode
1 answer:
Answer:
544.522 Hours
Explanation:
a) Mass = 12.5 kg = 12500 g
Now, Number of moles is given as
No of moles = Mass of Cr / Molar mass of Cr
= 240.38 moles
3 mols of electrons are required
Converting moles of e- to coulombs of charge, (1 mol of electrons = 96500 C )
Q =721.14 mol×96500 C/mol
=69590010 of charge
We know that, Q = I×t
where Q is charge, I is current and t is time required.
=196281.97 seconds
=544.522 Hours
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I think this reaction is forming 2,4,6- trinitrotoluene from benzene, since the product is not mentioned. Following are the steps to convert Benzene to 2,4,6 trinitrotoluene .
Step 1: Conversion of Benzene to Toluene .
Benzene can be converted to toluene by Friedel Craft Alkylation of benzene . In this reaction reagent AlCl₃ and Ch3Cl is used . Electrophile CH³⁺ is produced which attached on carbon of benzene and formation of Toluene and HCl occur.
Step 2 : Conversion of Toluene to dinitrotoluene.
Dinitritoluene is prepared from toluene by Nitration . This reaction uses Electrophilic substitution mechanism . The reagents used are HNO₃ and H₂SO₄ at room temperature . These reagents produces NO₂⁺ ( nitronium ion ), a electrophile which attacks on C2 and C4 Carbon atoms of Toluene.
Toluene
Step 3) Conversion of Dinitro toluene to trinitrotoluene.
This reaction is extended nitration of toluene . Further nitration is done in extreme condition . The temperature of reaction is increased to 90- 100 ⁰ C . Due to which there is more production of NO²⁺ ion occurs from HNO₃ -H₂SO₄ and they attack on C6 carbon atom of dinitrotoluene which forms 2,4,6- trinitrotoluene.
Dinitrotoluene
So over all reaction uses three reagents in order :
