When the Pka for formic acid = 3.77
and Pka = -㏒ Ka
3.77 = -㏒ Ka
∴Ka = 1.7x10^-4
when Ka = [H+][HCOO-}/[HCOOH]
when we have Ka = 1.7x10^-4 &[HCOOH] = 0.21 m
so by substitution: by using ICE table value
1.7x10^-4 = X*X / (0.21-X)
(1.7x10^-4)*(0.21-X) = X^2 by solving this equation for X
∴X = 0.0059
∴[H+] = 0.0059
∴PH= -㏒ [H+]
= -㏒ 0.0059
= 2.23
Answer:
Molar mass→ 0.930 g / 6.45×10⁻³ mol = 144.15 g/mol
Explanation:
Let's apply the formula for freezing point depression:
ΔT = Kf . m
ΔT = 74.2°C - 73.4°C → 0.8°C
Difference between the freezing T° of pure solvent and freezing T° of solution
Kf = Cryoscopic constant → 5.5°C/m
So, if we replace in the formula
ΔT = Kf . m → ΔT / Kf = m
0.8°C / 5.5 m/°C = m → 0.0516 mol/kg
These are the moles in 1 kg of solvent so let's find out the moles in our mass of solvent which is 0.125 kg
0.0516 mol/kg . 0.125 kg = 6.45×10⁻³ moles. Now we can determine the molar mass:
Molar mass (mol/kg) → 0.930 g / 6.45×10⁻³ mol = 144.15 g/mol
Answer:
curium
−
243
,
252
/
99
Es,
251
/
98
Cf,
214
/
82
Pb
Explanation: Im not very good with this but here ya go!
Answer:
a. electrophilic aromatic substitution
b. nucleophilic aromatic substitution
c. nucleophilic aromatic substitution
d. electrophilic aromatic substitution
e. nucleophilic aromatic substitution
f. electrophilic aromatic substitution
Explanation:
Electrophilic aromatic substitution is a type of chemical reaction where a hydrogen atom or a functional group that is attached to the aromatic ring is replaced by an electrophile. Electrophilic aromatic substitutions can be classified into five classes: 1-Halogenation: is the replacement of one or more hydrogen (H) atoms in an organic compound by a halogen such as, for example, bromine (bromination), chlorine (chlorination), etc; 2- Nitration: the replacement of H with a nitrate group (NO2); 3-Sulfonation: the replacement of H with a bisulfite (SO3H); 4-Friedel-CraftsAlkylation: the replacement of H with an alkyl group (R), and 5-Friedel-Crafts Acylation: the replacement of H with an acyl group (RCO). For example, the Benzene undergoes electrophilic substitution to produce a wide range of chemical compounds (chlorobenzene, nitrobenzene, benzene sulfonic acid, etc).
A nucleophilic aromatic substitution is a type of chemical reaction where an electron-rich nucleophile displaces a leaving group (for example, a halide on the aromatic ring). There are six types of nucleophilic substitution mechanisms: 1-the SNAr (addition-elimination) mechanism, whose name is due to the Hughes-Ingold symbol ''SN' and a unimolecular mechanism; 2-the SN1 reaction that produces diazonium salts 3-the benzyne mechanism that produce highly reactive species (including benzyne) derived from the aromatic ring by the replacement of two substituents; 4-the free radical SRN1 mechanism where a substituent on the aromatic ring is displaced by a nucleophile with the formation of intermediary free radical species; 5-the ANRORC (Addition of the Nucleophile, Ring Opening, and Ring Closure) mechanism, involved in reactions of metal amide nucleophiles and substituted pyrimidines; and 6-the Vicarious nucleophilic substitution, where a nucleophile displaces an H atom on the aromatic ring but without leaving groups (such as, for example, halogen substituents).
