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Andru [333]
3 years ago
7

Why is the brcl molecules polar??

Chemistry
2 answers:
Dahasolnce [82]3 years ago
6 0

The electronegativity value of Br and Cl is 2.8 and 3.0 respectively.  

The electrinegativity difference in the Br-Cl bond is 3.0 – 2.8 = 0.2

If the electronegativity difference is below 0.5 the covalent bind is nonpolar

If the electronegativity difference is between 0.5 and 2.0 the covalent bond is polar.

If the electronegativity difference is above 2.0 the bond is ionic  

As the electronegativity difference is below 0.5 the Br-Cl covalent bond is nonpolar

tester [92]3 years ago
5 0
<span>Because there is a permanent dipole between the Br and Cl atom. The Cl atom has a higher electronegativity, so it will tend to pull the "shared" electrons formed in the bond to its pole, creating a permanent dipole and partial electron deficiency on the bromine atom.</span>
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Answer:

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Explanation:

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Consider the reaction
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Answer :

(a) The average rate will be:

\frac{d[Br_2]}{dt}=9.36\times 10^{-5}M/s

(b) The average rate will be:

\frac{d[H^+]}{dt}=1.87\times 10^{-4}M/s

Explanation :

The general rate of reaction is,

aA+bB\rightarrow cC+dD

Rate of reaction : It is defined as the change in the concentration of any one of the reactants or products per unit time.

The expression for rate of reaction will be :

\text{Rate of disappearance of A}=-\frac{1}{a}\frac{d[A]}{dt}

\text{Rate of disappearance of B}=-\frac{1}{b}\frac{d[B]}{dt}

\text{Rate of formation of C}=+\frac{1}{c}\frac{d[C]}{dt}

\text{Rate of formation of D}=+\frac{1}{d}\frac{d[D]}{dt}

Rate=-\frac{1}{a}\frac{d[A]}{dt}=-\frac{1}{b}\frac{d[B]}{dt}=+\frac{1}{c}\frac{d[C]}{dt}=+\frac{1}{d}\frac{d[D]}{dt}

From this we conclude that,

In the rate of reaction, A and B are the reactants and C and D are the products.

a, b, c and d are the stoichiometric coefficient of A, B, C and D respectively.

The negative sign along with the reactant terms is used simply to show that the concentration of the reactant is decreasing and positive sign along with the product terms is used simply to show that the concentration of the product is increasing.

The given rate of reaction is,

5Br^-(aq)+BrO_3^-(aq)+6H^+(aq)\rightarrow 3Br_2(aq)+3H_2O(l)

The expression for rate of reaction :

\text{Rate of disappearance of }Br^-=-\frac{1}{5}\frac{d[Br^-]}{dt}

\text{Rate of disappearance of }BrO_3^-=-\frac{d[BrO_3^-]}{dt}

\text{Rate of disappearance of }H^+=-\frac{1}{6}\frac{d[H^+]}{dt}

\text{Rate of formation of }Br_2=+\frac{1}{3}\frac{d[Br_2]}{dt}

\text{Rate of formation of }H_2O=+\frac{1}{3}\frac{d[H_2O]}{dt}

Thus, the rate of reaction will be:

\text{Rate of reaction}=-\frac{1}{5}\frac{d[Br^-]}{dt}=-\frac{d[BrO_3^-]}{dt}=-\frac{1}{6}\frac{d[H^+]}{dt}=+\frac{1}{3}\frac{d[Br_2]}{dt}=+\frac{1}{3}\frac{d[H_2O]}{dt}

<u>Part (a) :</u>

<u>Given:</u>

\frac{1}{5}\frac{d[Br^-]}{dt}=1.56\times 10^{-4}M/s

As,  

-\frac{1}{5}\frac{d[Br^-]}{dt}=+\frac{1}{3}\frac{d[Br_2]}{dt}

and,

\frac{d[Br_2]}{dt}=\frac{3}{5}\frac{d[Br^-]}{dt}

\frac{d[Br_2]}{dt}=\frac{3}{5}\times 1.56\times 10^{-4}M/s

\frac{d[Br_2]}{dt}=9.36\times 10^{-5}M/s

<u>Part (b) :</u>

<u>Given:</u>

\frac{1}{5}\frac{d[Br^-]}{dt}=1.56\times 10^{-4}M/s

As,  

-\frac{1}{5}\frac{d[Br^-]}{dt}=-\frac{1}{6}\frac{d[H^+]}{dt}

and,

-\frac{1}{6}\frac{d[H^+]}{dt}=\frac{3}{5}\frac{d[Br^-]}{dt}

\frac{d[H^+]}{dt}=\frac{6}{5}\times 1.56\times 10^{-4}M/s

\frac{d[H^+]}{dt}=1.87\times 10^{-4}M/s

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