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kherson [118]
3 years ago
11

An ideal gas (C}R), flowing at 4 kmol/h, expands isothermally at 475 Kfrom 100 to 50 kPa through a rigid device. If the power pr

oduced is 2000 W, what is the corresponding rate of heat flow? What is the rate of lost work?
Chemistry
1 answer:
Zina [86]3 years ago
4 0

<u>Answer:</u> The rate of heat flow is 3.038 kW and the rate of lost work is 1.038 kW.

<u>Explanation:</u>

We are given:

C_p=\frac{7}{2}R\\\\T=475K\\P_1=100kPa\\P_2=50kPa

Rate of flow of ideal gas , n = 4 kmol/hr = \frac{4\times 1000mol}{3600s}=1.11mol/s    (Conversion factors used:  1 kmol = 1000 mol; 1 hr = 3600 s)

Power produced = 2000 W = 2 kW     (Conversion factor:  1 kW = 1000 W)

We know that:

\Delta U=0   (For isothermal process)

So, by applying first law of thermodynamics:

\Delta U=\Delta q-\Delta W

\Delta q=\Delta W      .......(1)

Now, calculating the work done for isothermal process, we use the equation:

\Delta W=nRT\ln (\frac{P_1}{P_2})

where,

\Delta W = change in work done

n = number of moles = 1.11 mol/s

R = Gas constant = 8.314 J/mol.K

T = temperature = 475 K

P_1 = initial pressure = 100 kPa

P_2 = final pressure = 50 kPa

Putting values in above equation, we get:

\Delta W=1.11mol/s\times 8.314J\times 475K\times \ln (\frac{100}{50})\\\\\Delta W=3038.45J/s=3.038kJ/s=3.038kW

Calculating the heat flow, we use equation 1, we get:

[ex]\Delta q=3.038kW[/tex]

Now, calculating the rate of lost work, we use the equation:

\text{Rate of lost work}=\Delta W-\text{Power produced}\\\\\text{Rate of lost work}=(3.038-2)kW\\\text{Rate of lost work}=1.038kW

Hence, the rate of heat flow is 3.038 kW and the rate of lost work is 1.038 kW.

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<u>Answer:</u> The balanced chemical equation is written below.

<u>Explanation:</u>

Galvanization is defined as the process in which a protective layer of zinc is applied to iron or steel to prevent the metal from rusting.

Zinc prevents the oxidation of iron and acts as a reducing agent in the process.

The half reaction for the process follows:

<u>Oxidation half reaction:</u>  Zn\rightarrow Zn^{2+}+2e^-

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6 0
3 years ago
Which solution below has the highest concentration of hydroxide ions?a. pH= 3.21b. pH= 7.00c. pH= 7.93d. pH= 12.59e. pH= 9.82
Sloan [31]

Answer:

  • <em>The solution that has the highest concentration of hydroxide ions is </em><u>d. pH = 12.59.</u>

Explanation:

You can solve this question using just some chemical facts:

  1. pH is a measure of acidity or alkalinity: the higher the pH the lower the acidity and the higher the alkalinity.
  2. The higher the concentration of hydroxide ions the lower the acidity or the higher the alkalinity of the solution, this is the higher the pH.

Hence, since you are asked to state the solution with the highest concentration of hydroxide ions, you just pick the highest pH. This is the option d, pH = 12.59.

These mathematical relations are used to find the exact concentrations of hydroxide ions:

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  • pOH = - log [OH⁻] ⇒ [OH^-]=10^{-pOH}

Then, you can follow these calculations:

Solution    pH        pOH                            [OH⁻]

a.               3.21       14 - 3.21 = 10.79        antilogarithm of 10.79 = 1.6 × 10⁻¹¹

b.               7.00      14 - 7.00 = 7.00        antilogarithm of 7.00 = 10⁻⁷

c.                7.93      14 - 7.93 = 6.07        antilogarithm of 6.07 = 8.5 × 10⁻⁷

d.               12.59     14 - 12.59 = 1.41        antilogarithm of 1.41 = 0.039

e.               9.82      14 - 9.82 = 4.18        antilogarithm of 4.18 = 6.6 × 10⁻⁵

From which you see that the highest concentration of hydroxide ions is for pH = 12.59.

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Answer:

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Explanation:

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Q = heat energy (Joules, J) m = mass of a substance (kg) c = specific heat (units J/g∙K)

∆ is a symbol meaning "the change in" ∆T = change in temperature (Kelvins, K)

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