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Marianna [84]
3 years ago
5

A solution of chloroform, CHCl3, and acetone, (CH3)2CO, exhibits a negative deviation from Raoult's law. This result implies tha

t
Chemistry
1 answer:
Gnoma [55]3 years ago
7 0

The given question is incomplete. The complete question is as follows.

A solution of chloroform (CHCl_{3}) and acetone ((CH_{3})_{2}CO) exhibits a negative deviation from Raoult's law. This result implies that:

chloroform-chloroform interactions are stronger than chloroform-acetone interactions.

chloroform-chloroform interactions are weaker than chloroform-acetone interactions.

acetone-acetone interactions are stronger than chloroform-acetone interactions.

acetone-acetone interactions are weaker than chloroform-acetone interactions

chloroform-chloroform interactions are weaker than chloroform-acetone interactions AND acetone-acetone interactions are weaker than chloroform-acetone interactions.

Explanation:

It is known that when the forces between the particles of the mixture are stronger than the forces between the particles in the pure liquids then negative deviations from Raoult's law are observed.

Hence, when a solution of chloroform (CHCl_{3}) and Acetone ((CH_{3})_{2}CO) will exhibit a negative deviation from Roult's law.

Then, chloroform-chloroform interactions should be weaker than chloroform-acetone interactions and acetone-acetone interactions must be weaker than Chloroform-Acetone interactions.

thus, we can conclude that for the given situation  chloroform-chloroform interactions are weaker than chloroform-acetone interactions AND acetone-acetone interactions are weaker than chloroform-acetone interactions.

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The decomposition of NI3 to form N2 and I2 releases −290.0 kJ of energy. The reaction can be represented as 2NI3(s)→N2(g)+3I2(g)
EastWind [94]

Answer:

-7.34 kilo Joules is the change in enthaply when 20.0 grams of nitrogen triiodide decomposes.

Explanation:

Mass of nitrogen triiodide = 20.0 g

Moles of nitrogen triiodide = \frac{20.0 g}{395 g/mol}=0.05063 mol

2NI_3(s)\rightarrow N_2(g)+3I_2(g), \Delta H_{rxn}=-290.0 kJ

According to reaction, 2 moles of nitrogen triiodide gives 290.0 kilo Joules of heat on decomposition ,then 0.05063 moles of nitrogen triiodide will give :

\frac{-290.0 kJ}{2}\times 0.05063=-7.34 kJ

-7.34 kilo Joules is the change in enthaply when 20.0 grams of nitrogen triiodide decomposes.

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3 years ago
A hot lump of 39.9 g of iron at an initial temperature of 78.1 °C is placed in 50.0 mL H 2 O initially at 25.0 °C and allowed to
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Answer : The final temperature of the mixture is 29.6^oC

Explanation :

In this problem we assumed that heat given by the hot body is equal to the heat taken by the cold body.

q_1=-q_2

m_1\times c_1\times (T_f-T_1)=-m_2\times c_2\times (T_f-T_2)

where,

c_1 = specific heat of iron = 0.499J/g^oC

c_2 = specific heat of water = 4.18J/g^oC

m_1 = mass of iron = 39.9 g

m_2 = mass of water  = Density\times Volume=1g/mL\times 50.0mL=50.0g

T_f = final temperature of mixture = ?

T_1 = initial temperature of iron = 78.1^oC

T_2 = initial temperature of water = 25.0^oC

Now put all the given values in the above formula, we get

(39.9g)\times (0.499J/g^oC)\times (T_f-78.1)^oC=-(50.0g)\times 4.18J/g^oC\times (T_f-25.0)^oC

T_f=29.6^oC

Therefore, the final temperature of the mixture is 29.6^oC

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