The amplitude of a wave is the distance between a point on one wave and the identical point on the next wave. The period and wavelength of a wave are inversely proportional.
The overall reaction is given by:
The fast step reaction is given as:
The slow step reaction is given as:
(slow step 
)
Now, the expression for the rate of reaction of fast reaction is:
![r_{1}=k_{1}[NO][Br_{2}]-k_{-1}[NOBr_{2}]](https://tex.z-dn.net/?f=r_%7B1%7D%3Dk_%7B1%7D%5BNO%5D%5BBr_%7B2%7D%5D-k_%7B-1%7D%5BNOBr_%7B2%7D%5D)
The expression for the rate of reaction of slow reaction is:
![r_{2}=k_{2}[NOBr_{2}] [NO]](https://tex.z-dn.net/?f=r_%7B2%7D%3Dk_%7B2%7D%5BNOBr_%7B2%7D%5D%20%5BNO%5D)
Slow step is the rate determining step. Thus, the overall rate of formation is the rate of formation of slow reaction as ![[NOBr_{2}]](https://tex.z-dn.net/?f=%5BNOBr_%7B2%7D%5D)
takes place in this reaction.
The expression of rate of formation is:
= ![k_{2}[NOBr_{2}][NO]](https://tex.z-dn.net/?f=k_%7B2%7D%5BNOBr_%7B2%7D%5D%5BNO%5D)
(1)
Now, consider that the fast step is always is in equilibrium. Therefore, 
![k_{1}[NO][Br_{2}]= k_{-1}[NOBr_{2}]](https://tex.z-dn.net/?f=k_%7B1%7D%5BNO%5D%5BBr_%7B2%7D%5D%3D%20k_%7B-1%7D%5BNOBr_%7B2%7D%5D)
![[NOBr_{2}] = \frac{k_{1}}{k_{-1}}[NO][Br_{2}]](https://tex.z-dn.net/?f=%5BNOBr_%7B2%7D%5D%20%3D%20%5Cfrac%7Bk_%7B1%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5BBr_%7B2%7D%5D)
Substitute the value of in equation (1), we get:
![\frac{d(NOBr)}{dt}=k_{2}[NOBr_{2}][NO]](https://tex.z-dn.net/?f=%5Cfrac%7Bd%28NOBr%29%7D%7Bdt%7D%3Dk_%7B2%7D%5BNOBr_%7B2%7D%5D%5BNO%5D)
=![k_{2} \frac{k_{1}}{k_{-1}}[NO][Br_{2}][NO]](https://tex.z-dn.net/?f=k_%7B2%7D%20%5Cfrac%7Bk_%7B1%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5BBr_%7B2%7D%5D%5BNO%5D)
= ![\frac{k_{1}k_{2}}{k_{-1}}[NO]^{2}[Br_{2}]](https://tex.z-dn.net/?f=%5Cfrac%7Bk_%7B1%7Dk_%7B2%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5E%7B2%7D%5BBr_%7B2%7D%5D)
Thus, rate law of formation of 
in terms of reactants is given by .
The amount
per 100 g is:
38.7 %
calcium = 38.7g Ca / 100g compound = 38.7g
19.9 %
phosphorus = 19.9g P / 100g compound = 19.9g
41.2 %
oxygen = 41.2g O / 100g compound = 41.2g
The molar amounts of calcium,
phosphorus and oxygen in 100g sample are calculated by dividing each element’s
mass by its molar mass:
Ca = 38.7/40.078
= 0.96
P = 19.9/30.97
= 0.64
O = 41.2/15.99
= 2.57
C0efficients
for the tentative empirical formula are derived by dividing each molar amount
by the lesser value that is 0.64 and in this case, after that multiply wih 2.
Ca = 0.96 /
0.64 = 1.5=1.5 x 2 = 3
P = 0.64 /
0.64 = 1 = 1x2= 2
O = 2.57 /
0.64 = 4= 4x2= 8
Since, the
resulting ratio is calcium 3, phosphorus 2 and oxygen 8
<span>So, the
empirical formula of the compound is Ca</span>₃(PO₄)₂
Iodine would have chemical properties most like Fluorine, Chlorine and other elements in group 7
