It is false. The salt bridge is not a path for electrons, but a path for ions to flow from one half-cell to another. It help to balance the charge between the oxidation and reduction vessels.
Answer:
36.8 L
Explanation:
We'll begin by converting 80 °C to Kelvin temperature. This can be obtained as follow:
T(K) = T(°C) + 273
T(°C) = 80 °C
T(K) = 80 + 273
T(K) = 353 K
Finally, we shall determine the volume occupied by the helium gas. This can be obtained as follow:
Number of mole (n) = 1.27 moles
Temperature (T) = 353 K
Pressure (P) = 1 atm
Gas constant (R) = 0.0821 atm.L/Kmol
Volume (V) =?
PV = nRT
1 × V = 1.27 × 0.0821 × 353
V = 36.8 L
Thus, the volume occupied by the helium gas is 36.8 L
The molarity of formic acid is 100 mM or
. The dissociation reaction of formic acid is as follows:

The expression for dissociation constant of the reaction will be:
![K_{a}=\frac{[HCOO^{-}][H^{+}]}{[HCOOH]}](https://tex.z-dn.net/?f=K_%7Ba%7D%3D%5Cfrac%7B%5BHCOO%5E%7B-%7D%5D%5BH%5E%7B%2B%7D%5D%7D%7B%5BHCOOH%5D%7D)
Rearranging,
![[HCOO^{-}]=\frac{K_{a}[HCOOH]}{[H^{+}]}](https://tex.z-dn.net/?f=%5BHCOO%5E%7B-%7D%5D%3D%5Cfrac%7BK_%7Ba%7D%5BHCOOH%5D%7D%7B%5BH%5E%7B%2B%7D%5D%7D)
Here, pH of solution is 4.15 thus, concentration of hydrogen ion will be:
![[H^{+}]=10^{-pH}=10^{-4.15}=7.08\times 10^{-5}M](https://tex.z-dn.net/?f=%5BH%5E%7B%2B%7D%5D%3D10%5E%7B-pH%7D%3D10%5E%7B-4.15%7D%3D7.08%5Ctimes%2010%5E%7B-5%7DM)
Similarly,
thus,

Putting the values,
![[HCOO^{-}]=\frac{(1.78\times 10^{-4}M)(100\times 10^{-3}M)}{(7.08\times 10^{-5}M}=0.2511 M](https://tex.z-dn.net/?f=%5BHCOO%5E%7B-%7D%5D%3D%5Cfrac%7B%281.78%5Ctimes%2010%5E%7B-4%7DM%29%28100%5Ctimes%2010%5E%7B-3%7DM%29%7D%7B%287.08%5Ctimes%2010%5E%7B-5%7DM%7D%3D0.2511%20M)
Therefore, the concentration of formate will be 0.2511 M.