Answer:
Explanation:
<em>0.5 i go to k12 i jus took the test</em>
Answer:
K = 137.55 atm/M.
Explanation:
- The relationship between gas pressure and the concentration of dissolved gas is given by Henry’s law:
<em>P = (K)(C)</em>
where P is the partial pressure of the gaseous solute above the solution (P = 1.0 atm).
k is a constant (Henry’s constant).
C is the concentration of the dissolved gas (C = 7.27 x 10⁻³ M).
∴ K = P/C = (1.0 atm)/(7.27 x 10⁻³ M) = 137.55 atm/M.
<u>Answer</u>:
Electric evaporator has been used to clean up the Chernobyl and 3 mile island accident.
<u>Explanation</u>:
About 14 years back, there was a puff of radioactive steam from the evaporator used in the "Three-mile island" nuclear plant. It took two years for the electric evaporator to clean up the 2.2 million gallons of water that have been destroyed because of the nuclear power plant accident.
The steam that came out of the electric evaporator carried a radioactive form of hydrogen and tritium with itself. Cost of clean up was $1 billion.
<h3><u>Full Question:</u></h3>
The following compound has been found effective in treating pain and inflammation (J. Med. Chem. 2007, 4222). Which sequence correctly ranks each carbonyl group in order of increasing reactivity toward nucleophilic addition?
A) 1 < 2 < 3
B) 2 < 3 < 1
C) 3 < 1 < 2
D) 1 < 3 < 2
<h3><u>Answer: </u></h3>
The rate of nucleophilic attack of carbonyl compounds is 2<3 <1.
Option B
<h3><u>Explanation. </u></h3>
Nucleophilic attack is explained as the attack of an electron rich radical to a carbonyl compound like aldehyde or a ketone. A nucleophile has a high electron density, so it searches for a electropositive atom where it can donate a portion of its electron density and become stable.
A carbonyl compound is a
hybridized carbon atom with a double bonded oxygen atom in it. The oxygen atom pulls a huge portion of electron density from carbon being very electropositive.
In a ketone, there are two factors that make it less likely to undergo a nucleophilic attack than aldehyde. Firstly, the steric hindrance of two carbon groups being attached with the carbonyl carbon makes it harder for the nucleophile to approach. Secondly, the electron push by the carbon groups attached makes the carbonyl carbon a bit less electropositive than the aldehyde one. So aldehydes are more reactive towards a nucleophilic addition reaction.