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3 years ago

6

354.4 g of chlorine gas (MW=70.9g/mol) is held in a vessel with a fixed volume of 70.0 L. What is the pressure of the gas in atm

ospheres if its temperature is 30.0 Celsius?

2 answers:

nexus9112 [7]3 years ago

6 0

Answer: 1.78

Explanation:

Katarina [22]3 years ago

4 0

Explanation:P = 1.73atm

mole(n) = mass in grams/ molecular weight

n = 354.4/ 70.9

n=4.8717mol

From PV =nRT

P=nRT/V

P= 4.8717×0.0821×303/70

P=1.73atm

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<h3><u>Getting</u><u> </u><u>to</u><u> </u><u>the</u><u> </u><u>equation</u><u>:</u></h3>

Calcium in water reacts vigorously to give a cloudy white <em>Precipitate</em><em> </em>(compound) called Calcium hydroxide alongwith the evolution of Hydrogen gas.

$\boxed{ \mathsf{Ca + H_2O \rightarrow Ca(OH)_2 + H_2}}$

- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -

<h3><u>Balancing</u><u> </u><u>the</u><u> </u><u>equation</u><u>:</u><u> </u></h3>

This reaction is not in it's balanced form! The number of atoms of Hydrogen on the left is 2 while that on the right is 4,I.e.,they're not equal.

Adding a 2 in front of H2O solves the problem by making the number of atoms of each element on both the sides equal.

$\mathsf{Ca +2 H_2O \rightarrow Ca(OH)_2 + H_2}$

- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -

<h3><u>Observations</u><u>:</u></h3>

Looking into the equation more carefully, we see:

<u><em>1</em><em> </em></u><em>atom</em><em> </em><em>of</em><em> </em><em>Calcium</em><em> </em><em>reacts</em><em> </em><em>with</em><em> </em><em><u>2</u></em><em> </em><em>molecules</em><em> </em><em>of</em><em> </em><em>water</em><em> </em><em>to</em><em> </em><em>give</em><em> </em><u><em>1</em><em> </em></u><em>molecule</em><em> </em><em>of</em><em> </em><em>Calcium</em><em> </em><em>Hydroxide</em><em> </em><em>alongwith</em><em> </em><em><u>1</u></em><em> </em><em>molecule</em><em> </em><em>of</em><em> </em><em>Hydrogen</em><em> </em><em>gas</em><em>.</em>

- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -

<h3><u>Gram</u><u> </u><u>atomic</u><u> </u><u>and</u><u> </u><u>molecular</u><u> </u><u>masses</u><u> </u></h3>

<u>Mass</u><u> </u><u>of</u><u> </u><u>one</u><u> </u><u>atom</u><u> </u><u>of</u><u> </u><u>Calcium</u><u> </u>= it's gram atomic mass

= 40 g

<u>Mass of one "molecule" of Hydrogen</u>

= it's Gram molecular mass

= gram mass of one atom × number of atoms in one molecule

= 1 × 2

= 2 g

So,

according to our observation:

One atoms of Calcium gives one molecule of Hydrogen <em>(during the particular reaction)</em>

=><u> 40g of Calcium gives = 2g of Hydrogen</u>

•°• 1 g of Calcium gives = $\frac{2}{40}$

= $\frac{1}{20}$ g Hydrogen

- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -

<h3><u>Answer</u><u>:</u></h3>

We're provided with 20g of Calcium,

=> 20g of Calcium gives = 20 × $\frac{1}{20}$ g H2

<u>= 1 g H2</u>

_______________

Hope this helps!

6 0

2 years ago