Answer:
Sry i am unable to see the attached picture but i hope this helps
Explanation:
There are a couple of ways to prepare a buffer solution of a specific pH. In the first method, prepare a solution with an acid and its conjugate base by dissolving the acid form of the buffer in about 60% of the volume of water required to obtain the final solution volume
Answer : The work, heat during the process and the change of entropy of the gas are, 0 J, 3333.003 J and -10 J respectively.
Explanation :
(a) At constant volume condition the entropy change of the gas is:

We know that,
The relation between the
for an ideal gas are :

As we are given :



Now we have to calculate the entropy change of the gas.


(b) As we know that, the work done for isochoric (constant volume) is equal to zero. 
(C) Heat during the process will be,

Therefore, the work, heat during the process and the change of entropy of the gas are, 0 J, 3333.003 J and -10 J respectively.
Also water H2O is made of H+ and OH- ions. so when an acidic substance is added to water the concentration of H+ ions increase.