Answer: (3) The difference in electronegativity between carbon and oxygen is greater than that between fluorine and oxygen.
Explanation: Polarity of a molecule is due to the difference in electronegativity of the atoms. More is the electronegativity difference, more is the polarity.
Electronegativity of carbon = 2.5
Electronegativity of oxygen = 3.5
Electronegativity of fluorine = 4.0
Thus the difference in electronegativity of carbon and oxygen is=(3.5-2.5)= 1.0
Thus the difference in electronegativity of fluorine and oxygen is=(4.0-3.5)= 0.5.
Thus C-O bond is more polar than F-O bond.
#b
According to Le C ha.te llors principle of we increase concentration of reactants or products equilibrium shifts.
#c
- Rate of reaction also increases
#e
Stated in b
Answer: Mass Of CFC that needs to evaporate for the freezing of water = 328.24 g
Explanation: Heat gained by the CFC = Heat lost by water
Heat lost by water = Heat required to take water's temperature to 0°c + Heat required to freeze water at 0°c
Heat required to take water's temperature from 33°c to 0°c = mCΔT
m = 201g, C = 4.18 J/(gK), ΔT = 33
mCΔT = 201 × 4.18 × 33 = 27725.94 J
Heat required to freeze water at 0°c = mL
m = 201g, L = 334 J/g
mL = 201 × 334 = 67134 J
Heat gained by CFC to vaporize = mH = 27725.94 + 67134 = 94859.94 J
H = 289 J/g, m = ?
m × 289 = 94859.9
m = 328.24 g
QED!!
Answer:
The most consistent mechanism is SN1.
Explanation:
The solvolysis of tert-butyl iodide in methanol will arise by the SN1 mechanism.
The reason for that is due the geometric structure of tert-butyl. The tertiary structure allows the formation of a stable carbocation, after the loss of the iodide ion. The carbocation will then be attacked by methanol molecules forming an eter.
