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babymother [125]

3 years ago

11

How are electrons excited and what happens when the electrons relax

1 answer:

serg [7]3 years ago

4 0

<span>When electrons are excited they get more energy and jump to higher orbitals. As they loose that energy that had excited them in the beginning, they tend to return to their original orbitals and the color that is given off is when this is occurring. </span>

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A chemist fills a reaction vessel with 9.20 atm nitrogen monoxide (NO) gas, 9.15 atm chlorine (CI) gas, and 7.70 atm nitrosyl ch

ivanzaharov [21]

Answer:

The reactions free energy $\Delta G = -49.36 kJ$

Explanation:

From the question we are told that

The pressure of (NO) is $P_{NO} = 9.20 \ atm$

The pressure of (Cl) gas is $P_{Cl} = 9.15 \ atm$

The pressure of nitrosly chloride (NOCl) is $P_{(NOCl)} = 7.70 \ atm$

The reaction is

$2NO_{(g)} + Cl_2 (g)$ ⇆ $2 NOCl_{(g)}$

From the reaction we can mathematically evaluate the $\Delta G^o$ (Standard state free energy ) as

$\Delta G^o = 2 \Delta G^o _{NOCl} - \Delta G^o _{Cl_2} - 2 \Delta G^o _{NO}$

The Standard state free energy for NO is constant with a value

$\Delta G^o _{NO} = 86.55 kJ/mol$

The Standard state free energy for $Cl_2$ is constant with a value

$\Delta G^o _{Cl_2} = 0kJ/mol$

The Standard state free energy for $NOCl$ is constant with a value

$\Delta G^o _{NOCl} =66.1kJ/mol$

Now substituting this into the equation

$\Delta G^o = 2 * 66.1 - 0 - 2 * 87.6$

$= -43 kJ/mol$

The pressure constant is evaluated as

$Q = \frac{Pressure \ of \ product }{ Pressure \ of \ reactant }$

Substituting values

$Q = \frac{(7.7)^2 }{(9.2)^2 (9.15) } = \frac{59.29}{774.456}$

$= 0.0765$

The free energy for this reaction is evaluated as

$\Delta G = \Delta G^o + RT ln Q$

Where R is gas constant with a value of $R = 8.314 J / K \cdot mol$

T is temperature in K with a given value of $T = 25+273 = 298 K$

Substituting value

$\Delta G = -43 *10^{3} + 8.314 *298 * ln [0.0765]$

$= -43-6.36$

$\Delta G = -49.36 kJ$

4 0

3 years ago