It's pretty easy to balance equations! Basically you want to make sure that the number of each compound is equal on both sides of the arrow.
For example number one is
Fe + H2SO4 -> Fe2(SO4)3 + H2
A 3 in front of H2SO4 because there's a subscript of 3 on the right side.
Then a 3 in front of H2 because of the previous step.
Then add a 2 in front of Fe because of the 2 subscript in Fe2(SO4)3
Then add a 1 in front of Fe2(SO4)3 because you already have an equal number of each element.
<u>2</u>Fe + <u>3</u>H2SO4 -> <u>1</u>Fe2(SO4)3 + <u>3</u>H2
I hope this explanation helps! You should really do your homework because practice is everything when it comes to chemistry. You'll need to know how to do it for exams.
The middle nitrogen has two sigma bonds and one pi bond. You know that one p orbital is used in the double bond and two sp2 orbitals are involved in the sigma bond. This leaves one sp2 orbital for the lone pair to occupy.