Answer:
Mass percent N₂ = 89%
Mass percent H₂ = 11%
Explanation:
First we <u>use PV=nRT to calculate n</u>, which is the total number of moles of nitrogen and hydrogen:
- 1.03 atm * 7.45 L = n * 0.082 atm·L·mol⁻¹·K⁻¹ * 305 K
So now we know that
- MolH₂ + MolN₂ = 0.307 mol
and
- MolH₂ * 2 g/mol + MolN₂ * 28 g/mol = 3.49 g
So we have a <u>system of two equations and two unknowns</u>. We use algebra to solve it:
Express MolH₂ in terms of MolN₂:
- MolH₂ + MolN₂ = 0.307 mol
Replace that value in the second equation:
- MolH₂ * 2 g/mol + MolN₂ * 28 g/mol = 3.49
- (0.307-MolN₂) * 2 + MolN₂ * 28 = 3.49
- 0.614 - 2MolN₂ + 28molN₂ = 3.49
Now we calculate MolH₂:
- MolH₂ + MolN₂ = 0.307 mol
Finally, we convert each of those mol numbers to mass, to <u>calculate the mass percent</u>:
- N₂ ⇒ 0.111 mol * 28 g/mol = 3.108 g N₂
- H₂ ⇒ 0.196 mol * 2 g/mol = 0.392 g H₂
Mass % N₂ = 3.108/3.49 * 100% = 89.05% ≅ 89%
Mass % H₂ = 0.392/3.49 * 100% = 11.15% ≅ 11%
Equilibrium expression is ![Keq = \frac{[H3O+][HCO3^-]}{[H2CO3]}\\](https://tex.z-dn.net/?f=Keq%20%3D%20%5Cfrac%7B%5BH3O%2B%5D%5BHCO3%5E-%5D%7D%7B%5BH2CO3%5D%7D%5C%5C)
<u>Explanation:</u>
Equilibrium expression is denoted by Keq.
Keq is the equilibrium constant that is defined as the ratio of concentration of products to the concentration of reactants each raised to the power its stoichiometric coefficients.
Example -
aA + bB = cC + dD
So, Keq = conc of product/ conc of reactant
![Keq = \frac{[C]^c [D]^d}{[A]^a [B]^b}](https://tex.z-dn.net/?f=Keq%20%3D%20%5Cfrac%7B%5BC%5D%5Ec%20%5BD%5D%5Ed%7D%7B%5BA%5D%5Ea%20%5BB%5D%5Eb%7D)
So from the equation, H₂CO₃+H₂O = H₃O+HCO₃⁻¹
![Keq = \frac{[H3O^+]^1 [HCO3^-]^1}{[H2CO3]^1 [H2O]^1}](https://tex.z-dn.net/?f=Keq%20%3D%20%5Cfrac%7B%5BH3O%5E%2B%5D%5E1%20%5BHCO3%5E-%5D%5E1%7D%7B%5BH2CO3%5D%5E1%20%5BH2O%5D%5E1%7D)
The concentration of pure solid and liquid is considered as 1. Therefore, concentration of H2O is 1.
Thus,
Therefore, Equilibrium expression is
Answer:
0.08 mol L-1
Explanation:
Sulfuric acid Formula: H2SO4
Ammonia Formula: NH3
Ammonium sulfate Formula: (NH₄)₂SO₄
H2SO4 + 2NH3 = 2NH4+ + SO4 2-
H2SO4 + 2NH3 = (NH₄)₂SO₄
H2SO4 = (1/2)x (32.8 x 10^-3 L x 0.116 mol L-1)/25 x 10^-3 L
= 0.08 mol L-1
