Physical Change: It is a type of change in which matter changes its physical state like shape, size but is not transformed into another substance. It is usually a reversible process.
Chemical Change: It is a type of change in which the rearrangement of atoms of one or more than one substance is involved. and it changes its chemical composition that is there is a formation of at least one new substance. It is usually an irreversible process.
Now, keeping in mind the definitions, we can easily classify the examples in the question as physical or chemical change.
You simply add the volumes :) If this was a case that involved titration, you would use the formula M1V1 = M2V2. I do not know if that is what you were referring to but based on the information you gave, you simply add the two volumes.
