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Enthalpy of formation is calculated by subtracting the total enthalpy of formation of the reactants from those of the products. This is called the HESS' LAW.
ΔHrxn = ΔH(products) - ΔH(reactants)
Since the enthalpies are not listed in this item, from reliable sources, the obtained enthalpies of formation are written below.
ΔH(C2H5OH) = -276 kJ/mol
ΔH(O2) = 0 (because O2 is a pure substance)
ΔH(CO2) = -393.5 kJ/mol
ΔH(H2O) = -285.5 kJ/mol
Using the equation above,
ΔHrxn = (2)(-393.5 kJ/mol) + (3)(-285.5 kJ/mol) - (-276 kJ/mol)
ΔHrxn = -1367.5 kJ/mol
<em>Answer: -1367.5 kJ/mol</em>
Answer
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Precipitation occurs when the product of the ion concentration exceeds the Ksp.