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Nostrana [21]
3 years ago
7

A lab technician has 45L gas in a flexible container at a pressure of 100.0 kPa. If the technician decreases the pressure to 60.

0 kPa, without changing the temperature, what is the new volume?
Chemistry
1 answer:
ICE Princess25 [194]3 years ago
5 0

Answer:

75 L

Explanation:

We assume that the gas in the container is an ideal gas, which is governed by the ideal gas equation : PV = nRT , where P is the pressure of the gas, V is the volume of the container, n is the number of mols of the gas, R is the universal gas constant and T is the temperature of the gas.

Here, R is a universal constant with a value of ≈ 8.314 J/mol-K. Also, given that temperature (T) is maintained constant. And since the container is closed, there is no exchange of the gas between the container and the surroundings, thus keeping the number of mols (n) of the gas constant. Hence, in the ideal gas equation, right hand side, i.e, nRT is a constant.

Initially the equation is: P_{1}V_{1} = nRT(constant)

Finally, the equation is:P_{2}V_{2} = nRT(constant)

Since, nRT is a constant, P_{1}V_{1} = P_{2}V_{2}

It is given that, P_{1} = 100.0KPa , V_{1} = 45L and P_{2} = 60.0KPa.

Therefore, 100x45 = 60 x V_{2} ⇒ V_{2} = 75L

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A 13.5g sample of gold is heated, then placed in a calorimeter containing 60g of water. The temperature of water increases from
sweet-ann [11.9K]

Answer:

T_i~=163.1 ºC

Explanation:

We have to start with the variables of the problem:

Mass of water = 60 g

Mass of gold = 13.5 g

Initial temperature of water= 19 ºC

Final temperature of water= 20 ºC

<u>Initial temperature of gold= Unknow</u>

Final temperature of gold= 20 ºC

Specific heat of gold = 0.13J/gºC

Specific heat of water = 4.186 J/g°C

Now if we remember the <u>heat equation</u>:

Q_H_2_O=m_H_2_O*Cp_H_2_O*deltaT

Q_A_u=m_A_u*Cp_A_u*deltaT

We can relate these equations if we take into account that <u>all heat of gold is transfer to the water</u>, so:

m_H_2_O*Cp_H_2_O*deltaT=~-~m_A_u*Cp_A_u*deltaT

Now we can <u>put the values into the equation</u>:

60~g*4.186~J/g{\circ}C*(20-19)~{\circ}C=-(13.5~g*0.13~J/g{\circ}C*(20-T_i)~{\circ}C)

Now we can <u>solve for the initial temperature of gold</u>, so:

T_i~=(\frac{60~g*4.186~J/g{\circ}C*(20-19)~{\circ}C}{13.5~g*0.13~J/g{\circ}C})+20

T_i~=163.1 ºC

I hope it helps!

5 0
3 years ago
Sulfuryl dichloride is formed when sulfur dioxide reacts with chlorine.
zubka84 [21]

<u>Answer:</u> The value of \Delta G^o of the reaction is 28.38 kJ/mol

<u>Explanation:</u>

For the given chemical reaction:

SO_2(g)+Cl_2(g)\rightarrow SO_2Cl_2(g)

  • The equation used to calculate enthalpy change is of a reaction is:

\Delta H^o_{rxn}=\sum [n\times \Delta H^o_f_{(product)}]-\sum [n\times \Delta H^o_f_{(reactant)}]

The equation for the enthalpy change of the above reaction is:

\Delta H^o_{rxn}=[(1\times \Delta H^o_f_{(SO_2Cl_2(g))})]-[(1\times \Delta H^o_f_{(SO_2(g))})+(1\times \Delta H^o_f_{(Cl_2(g))})]

We are given:

\Delta H^o_f_{(SO_2Cl_2(g))}=-364kJ/mol\\\Delta H^o_f_{(SO_2(g))}=-296.8kJ/mol\\\Delta H^o_f_{(Cl_2(g))}=0kJ/mol

Putting values in above equation, we get:

\Delta H^o_{rxn}=[(1\times (-364))]-[(1\times (-296.8))+(1\times 0)]=-67.2kJ/mol=-67200J/mol

  • The equation used to calculate entropy change is of a reaction is:

\Delta S^o_{rxn}=\sum [n\times \Delta S^o_f_{(product)}]-\sum [n\times \Delta S^o_f_{(reactant)}]

The equation for the entropy change of the above reaction is:

\Delta S^o_{rxn}=[(1\times \Delta S^o_{(SO_2Cl_2(g))})]-[(1\times \Delta S^o_{(SO_2(g))})+(1\times \Delta S^o_{(Cl_2(g))})]

We are given:

\Delta S^o_{(SO_2Cl_2(g))}=311.9J/Kmol\\\Delta S^o_{(SO_2(g))}=248.2J/Kmol\\\Delta S^o_{(Cl_2(g))}=223.0J/Kmol

Putting values in above equation, we get:

\Delta S^o_{rxn}=[(1\times 311.9)]-[(1\times 248.2)+(1\times 223.0)]=-159.3J/Kmol

To calculate the standard Gibbs's free energy of the reaction, we use the equation:

\Delta G^o_{rxn}=\Delta H^o_{rxn}-T\Delta S^o_{rxn}

where,

\Delta H^o_{rxn} = standard enthalpy change of the reaction =-67200 J/mol

\Delta S^o_{rxn} = standard entropy change of the reaction =-159.3 J/Kmol

Temperature of the reaction = 600 K

Putting values in above equation, we get:

\Delta G^o_{rxn}=-67200-(600\times (-159.3))\\\\\Delta G^o_{rxn}=28380J/mol=28.38kJ/mol

Hence, the value of \Delta G^o of the reaction is 28.38 kJ/mol

7 0
3 years ago
A gold nugget has a volume of 20.0 cm3 and its density is 19.3 g/cm3. What is the mass of the gold nugget?
salantis [7]
Density * Volume = Mass

Now we substitute the values in.

19.3 g/cm^3 + 20 cm^3 = 386 g

Mass = 386 g
5 0
3 years ago
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alina1380 [7]

Answer:

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8 0
2 years ago
calculate δg o for each reaction using δg o f values: (a) h2(g) i2(s) → 2hi(g) 2.6 kj (b) mno2(s) 2co(g) → mn(s) 2co2(g) kj (c)
Reika [66]

(a)The change in Gibbs free energy for the reaction has been 2.6 kJ/mol.

(b) The change in Gibbs free energy for the reaction has been -49.3 kJ/mol.

(c) The change in Gibbs free energy for the reaction has been 91.38 kJ/mol.

6 0
2 years ago
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