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3 years ago

Why the mixture should not be strongly heated during sublimation

Chemistry

1 answer:

daser333 [38]3 years ago

6 0

Answer:

because strong heated makes temperatures and pressures reach the substance's triple point in its phase diagram, So the substance can be in a liquid case , and that is against the sublimation process meaning

which define as the transition of a matter or a substance from the solid phase to the gas phase directly, without passing through the intermediate liquid phase

sublimation process happens by absorbing of heat which makes molecules overcome attractive force between each other and changing to gas phase

but in the previous case it will pass through the liquid phase so it will not be sublimation process any more

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The fizz produced when an Alka-Seltzer® tablet is dissolved in water is due to the reaction between sodium bicarbonate (NaHCO3)

cestrela7 [59]

Answer:

a. The limiting reactant is $NaHCO_{3}$

b. 0.73 g of carbon dioxide are formed.

c. The grams of excess reactant that do not participate in the reaction are 0333 g.

Explanation:

You know the following reaction:

$3NaHCO_{3} +H_{3} C_{6} H_{5} O_{7}$ ⇒ $3CO_{2} +3H_{2} O+Na_{3} C_{6} H_{5} O_{7}$

First, you determine the molar mass of each compound. For that you must take into account the atomic mass of each element:

Na: 23
H: 1
C: 12
O: 16

To determine the molar mass of each compound, you multiply the most atomic of each element present in the molecule by the sub-index that appears after each number, which indicates the present amount of each element in the compound:

$NaHCO_{3}$ :23+1+12+16*3=84 g/mol
$H_{3} C_{6} HO_{7}$ :1*3+12*6+1*5+16*7= 192 g/mol
$CO_{2}$ :12+16*2= 44 g/mol
$H_{2} O$ :1*2+16= 18 g/mol
$Na_{3} C_{6} H_{5} O_{7}$ : 23*3+12*6+1*5+16*7= 258 g/mol

By stoichiometry of the reaction (that is, the relationship between the amount of reagents and products in a chemical reaction), you know that 3 moles of $NaHCO_{3}$ react with 1 mole of $H_{3} C_{6} HO_{7}$ Then, taking into account the molar mass of each compound, you can calculate the reacting mass of each compound by stoichiometry:

$NaHCO_{3}$ : 252 g
$H_{3} C_{6} HO_{7}$ : 192 g

You know that in a certain experiment you have 1.40 g of sodium bicarbonate and 1.40 g of citric acid. To determine the limiting reagent apply a rule of three simple as follows:

If by stoichiometry 252 g of sodium bicarbonate react with 192 g of citric acid, how many grams of sodium bicarbonate react with 1.4 grams of citric acid?

$grams of sodium bicarbonate= \frac{1.4 g*252 g}{192 g}$

grams of sodium bicarbonate= 1.8375 g

But to perform the experiment you have only 1.4 g of sodium bicarbonate. So the limiting reagent is sodium bicarbonate.

As mentioned, the limiting reagent is sodium bicarbonate. This means that you should use 1.4 g of sodium bicarbonate for all subsequent calculations, because this compound is the reagent that will be consumed first.

Now, by stoichiometry of the reaction, you know that 3 moles of $NaHCO_{3}$ react with 3 mole of $CO_{2}$ . Then, taking into account the molar mass of each compound, you can calculate the reacting mass of each compound by stoichiometry:

$NaHCO_{3}$ : 252 g
$H_{3} C_{6} HO_{7}$ : 132 g

You make a simple rule of three: if 252 g of sodium bicarbonate form 132 g of carbon dioxide per stochetry, how many grams will form 1.4 g of sodium bicarbonate?

$grams of carbon dioxide =\frac{1.4 g * 132 g}{252 g}$

grams of carbon dioxide= 0.73 g

Then, 0.73 g of carbon dioxide are formed.

To know how much citric acid will react you apply a rule of three, taking into account as in the previous cases the stoichiometry of the reaction: If by stoichiometry 252 g of sodium bicarbonate react with 192 g of citric acid, how many grams of citric acid will they react with 1.4 g of sodium bicarbonate?

$grams of citric acid=\frac{1.4 g * 192 g}{252 g}$

grams of citric acid= 1.067 g

But you have 1.4 g of citric acid. That means that the grams you have minus the grams that react will be the grams that remain in excess and do not participate in the reaction:

grams of excess reactant=1.4 g - 1.067 g

grams of excess reactant=0.333 g

So the grams of excess reactant that do not participate in the reaction are 0333 g.

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3 years ago

Can any one please help me to answers this question i don't get it. thank in advance.

alex41 [277]

First, lets balance the reaction equation:
4Fe + 3O₂ → 2Fe₂O₃
It is visible form the equation that 4 moles of Fe require 3 moles of O₂
Molar ratio Fe/O₂ = 4/3 = 1.33
Molar ratio O₂/Fe = 3/4 = 0.75
Now, we check the molar ratios present:
Fe/O₂ = 6.8/8.9 = 0.76
O₂/Fe = 1.31

Thus, Iron is the limiting reactant because its ratio is not being fulfilled while the ratio of O₂ is surpassed.

8 0

3 years ago

Why the mixture should not be strongly heated during sublimation ​

Why the mixture should not be strongly heated during sublimation