1. Weird things like the one described above do not happen on a ramdom basis becuause molecules usually move within any enclosure in a ramdom manner. Thus, it is not possible for some types of particles to aggregate in one point while other types of molecule aggreagate in another point. Based on the kinetic energy that is available for each particle, each particle will move random
through the available space, colliding with one another and with the wall of container.
2. It will be a difficult thing to live in a Maxwell' demon world because, things will happen unpredictably and one will never know what to expect next because anything can happen at anytime. For instance, if one is drinking a glass of water, some of the particles of the water may just decide to aggregate to one part of the cup and start boiling. So, for someone who is taking a glass of water, the water may start boiling right inside his mouth when he is drinking, that will be a bad experience. When one is driving a car, the petrol particles may just decide to freeze up when one is busy speeding on the highway; that can cause a very serious accident. Thus, a world where the Maxwell law operates will be a chaotic world.
Because that's where they come from. Coal, oil, and natural gas are the products
of dead dinosaurs rotting in the ground under great pressure for millions of years.
Answer:
a.Phenols have the ability to spread out the negative charge that forms.
Explanation:
This happens because of the aromatic ring the phenols have. When loosing the proton, the anion formed have different resonance isomers due to the double bonds in the aromatic ring. This resonance makes the anion more stable and prevents the reaction going backwards.
On the other hand, regular alcohol doesn't have resonace and the reaction of loosing the proton goes leftward and righward: is in equilibrium.
That equilibrium decreases the acidity of the alcohol.
Answer : The fraction of carbonic acid present in the blood is 5.95%
Explanation :
The mixture consists of carbonic acid ( H₂CO₃) and bicarbonate ion ( HCO₃⁻). This represents a mixture of weak acid and its conjugate which is a buffer.
The pH of a buffer is calculated using Henderson equation which is given below.
![pH = pKa + log \frac{[Base]}{[Acid]}](https://tex.z-dn.net/?f=pH%20%3D%20pKa%20%2B%20log%20%5Cfrac%7B%5BBase%5D%7D%7B%5BAcid%5D%7D)
We have been given,
pH = 7.5
pKa of carbonic acid = 6.3
Let us plug in the values in Henderson equation to find the ratio Base/Acid.
![7.5 = 6.3 + log \frac{[base]}{[acid]}](https://tex.z-dn.net/?f=7.5%20%3D%206.3%20%2B%20log%20%5Cfrac%7B%5Bbase%5D%7D%7B%5Bacid%5D%7D)
![1.2 = log \frac{[base]}{[acid]}](https://tex.z-dn.net/?f=1.2%20%3D%20log%20%5Cfrac%7B%5Bbase%5D%7D%7B%5Bacid%5D%7D)
![\frac{[Base]}{[Acid]} = 10^{1.2}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BBase%5D%7D%7B%5BAcid%5D%7D%20%3D%2010%5E%7B1.2%7D)
![\frac{[Base]}{[Acid]} = 15.8](https://tex.z-dn.net/?f=%5Cfrac%7B%5BBase%5D%7D%7B%5BAcid%5D%7D%20%3D%2015.8)
![[Base] = 15.8 \times [Acid]](https://tex.z-dn.net/?f=%5BBase%5D%20%3D%2015.8%20%5Ctimes%20%5BAcid%5D)
The total of mole fraction of acid and base is 1. Therefore we have,
![[Acid] + [Base] = 1](https://tex.z-dn.net/?f=%5BAcid%5D%20%2B%20%5BBase%5D%20%3D%201)
But Base = 15.8 x [Acid]. Let us plug in this value in above equation.
![[Acid] + 15.8 \times [Acid] = 1](https://tex.z-dn.net/?f=%5BAcid%5D%20%2B%2015.8%20%5Ctimes%20%5BAcid%5D%20%3D%201)
![16.8 [Acid] = 1](https://tex.z-dn.net/?f=16.8%20%5BAcid%5D%20%3D%201)
![[Acid] = \frac{1}{16.8}](https://tex.z-dn.net/?f=%5BAcid%5D%20%3D%20%5Cfrac%7B1%7D%7B16.8%7D)
![[Acid] = 0.0595](https://tex.z-dn.net/?f=%5BAcid%5D%20%3D%200.0595)
[Acid] = 0.0595 x 100 = 5.95 %
The fraction of carbonic acid present in the blood is 5.95%