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sergiy2304 [10]
3 years ago
10

Consider the following reaction: CO(g)+2H2(g)⇌CH3OH(g) This reaction is carried out at a different temperature with initial conc

entrations of [CO]=0.27M and [H2]=0.49M. At equilibrium, the concentration of CH3OH is 0.11 M. Find the equilibrium constant at this temperature.
Chemistry
1 answer:
Anni [7]3 years ago
7 0

Answer:

Ka = 4.76108

Explanation:

  • CO(g) + 2H2(g) ↔ CH3OH(g)

∴ Keq = [CH3OH(g)] / [H2(g)]²[CO(g)]

                      [ ]initial         change         [ ]eq

CO(g)              0.27 M       0.27 - x        0.27 - x

H2(g)              0.49 M       0.49 - x        0.49 - x

CH3OH(g)          0                0 + x               x = 0.11 M

replacing in Ka:

⇒ Ka = ( x ) / (0.49 - x)²(0.27 - x)

⇒ Ka = (0.11) / (0.49 - 0.11)² (0.27 - 0.11)

⇒ Ka = (0.11) / (0.38)²(0.16)

⇒ Ka = 4.76108

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antoniya [11.8K]

Answer: The value of E^{o} for the half-cell reaction is 0.222 V.

Explanation:

Equation for solubility equilibrium is as follows.

          AgCl(s) \rightleftharpoons Ag^{+}(aq) + Cl^{-}(aq)

Its solubility product will be as follows.

       K_{sp} = [Ag^{+}][Cl^{-}]

Cell reaction for this equation is as follows.

     Ag(s)| AgCl(s)|Cl^{-}(0.1 M)|| Ag^{+}(1.0 M)| Ag(s)

Reduction half-reaction: Ag^{+} + 1e^{-} \rightarrow Ag(s),  E^{o}_{Ag^{+}/Ag} = 0.799 V

Oxidation half-reaction: Ag(s) + Cl^{-}(aq) \rightarrow AgCl(s) + 1e^{-},   E^{o}_{AgCl/Ag} = ?

Cell reaction: Ag^{+}(aq) + Cl^{-}(aq) \rightarrow AgCl(s)

So, for this cell reaction the number of moles of electrons transferred are n = 1.

    Solubility product, K_{sp} = [Ag^{+}][Cl^{-}]

                                               = 1.77 \times 10^{-10}

Therefore, according to the Nernst equation

           E_{cell} = E^{o}_{cell} - \frac{0.0592 V}{n} log \frac{[AgCl]}{[Ag^{+}][Cl^{-}]}

At equilibrium, E_{cell} = 0.00 V

Putting the given values into the above formula as follows.

         E_{cell} = E^{o}_{cell} - \frac{0.0592 V}{n} log \frac{[AgCl]}{[Ag^{+}][Cl^{-}]}

        0.00 = E^{o}_{cell} - \frac{0.0592 V}{1} log \frac{1}{[Ag^{+}][Cl^{-}]}    

       E^{o}_{cell} = \frac{0.0592}{1} log \frac{1}{K_{sp}}

                  = 0.0591 V \times log \frac{1}{1.77 \times 10^{-10}}

                  = 0.577 V

Hence, we will calculate the standard cell potential as follows.

           E^{o}_{cell} = E^{o}_{cathode} - E^{o}_{anode}

       0.577 V = E^{o}_{Ag^{+}/Ag} - E^{o}_{AgCl/Ag}

       0.577 V = 0.799 V - E^{o}_{AgCl/Ag}

       E^{o}_{AgCl/Ag} = 0.222 V

Thus, we can conclude that value of E^{o} for the half-cell reaction is 0.222 V.

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navik [9.2K]

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lutik1710 [3]
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8 0
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A solution contains an unknown mass of dissolved barium ions. When sodium sulfate is added to the solution, a white precipitate
AlladinOne [14]

The given question is incomplete. The complete question is as follows.

A solution contains an unknown mass of dissolved barium ions. When sodium sulfate is added to the solution, a white precipitate forms. The precipitate is filtered and dried and then found to have a mass of 212 mg. What mass of barium was in the original solution? (Assume that all of the barium was precipitated out of solution by the reaction.)

Explanation:

When Ba^{2+} and Na_{2}SO_{4} are added  then white precipitate forms. And, reaction equation for this is as follows.

       Ba^{2+} + SO^{2-}_{4} \rightarrow BaSO_{4}

It is given that mass (m) is 212 mg or 0.212 g (as 1 g = 1000 mg). Molecular weight of BaSO_{4} is 233.43.

Now, we will calculate the number of moles as follows.

  No. of moles = mass × M.W

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Hence, it means that 0.00091 mol of Ba^{2+}. Now, we will calculate the mass as follows.

       Mass = moles × MW

                 = 0.00091 \times 137.327

                 = 0.124 grams or 124 mg of barium

Thus, we can conclude that mass of barium into the original solution is 124 mg.

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klasskru [66]

Answer:

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Explanation:

We want to balance the given equation;

H₂ + CuO → Cu(OH)₂ + H₂O

To balance this we have to make sure the number of each element on the left is equal to the number of each element on the right.

Thus, the correct balanced equation is;

H₂ + CuO → Cu + H₂O

5 0
2 years ago
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