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kobusy [5.1K]
3 years ago
10

Which of these pairs indicates an incorrect coupling of reversible reactions?dehydration synthesis and hydrolysisanabolic and ca

tabolichydrolysis and breakdownbreakdown and synthesis
Chemistry
1 answer:
Olegator [25]3 years ago
8 0

Answer:

option C= hydrolysis and break down

Explanation:

All other three pairs are correct coupling of each others.

Option A= dehydration synthesis and hydrolysis

Dehydration synthesis:

In dehydration synthesis monomers combine through the covalent bonds and form large molecules. The large molecules are called polymers. The water as a byproduct also released when monomers joints together.

Hydrolysis:

In hydrolysis the polymers are break down into monomers by using water molecules. The catalysts are also required in this process.

Option B= Catabolic and Anabolic

Anabolic:

In this process smaller molecules combine to gather to form large complex molecules by using energy.

For example simple glucose molecules join together to form large disaccharides.

Catabolic:

It is the break down of large complex molecules to the smaller molecules.

For example during cellular respiration sugar molecules break down and generate energy.

Option D=  Break down and synthesis

The break down and synthesis are also reverse pair of each others. The  synthesis involve the formation of molecules form smaller component while the break down involve destruction of molecules into smaller units.

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A solution is prepared by mixing 250 mL of 1.00 M CH3COOH with 500 mL of 1.00 M NaCH3COO. What is the pH of this solution? (Ka f
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Answer:

A solution is prepared by mixing 250 mL of 1.00 M

CH3COOH with 500 mL of 1.00 M NaCH3COO.

What is the pH of this solution?

(Ka for CH3COOH = 1.8 × 10−5 )

Explanation:

This is a case of a neutralization reaction that takes place between acetic acid,     CH 3 COOH ,   a weak acid, and sodium hydroxide,   NaOH , a strong base.

The resulting solution pH, depends if the neutralization is complete or not.  If not, that is, if the acid is not completely neutralized, a buffer solution containing acetic acid will be gotten, and its conjugate base, the acetate anion.

It's important to note that at complete neutralization, the pH of the solution will not equal  7 . Even if the weak acid is neutralized completely, the solution will be left with its conjugate base, this is the reason why the expectations of its pH is to be over  7 .

So, the balanced chemical equation for this reaction is the ionic equation:

CH 3 COOH (aq]  +  OH − (aq]  →  CH 3 COO − (aq]  +  H 2 O (l]

Notice that:  

1  mole of acetic acid will react with:  1  mole of sodium hydroxide, shown here as hydroxide anions,  OH − , to produce   1   mole of acetate anions:

CH 3 COO −

To determine how many moles of each you're adding , the molarities and volumes of the two solutions are used:

     c  =  n /  V    ⇒     n   =   c  ⋅  V

n  acetic   =   0.20 M   ⋅   25.00   ⋅   10  − 3 L   =   0.0050 moles CH3 COOH

and

n  hydroxide   =   0.10 M   ⋅   40.00   ⋅   10 − 3 L   =   0.0040 moles OH −

There are fewer moles of hydroxide anions, so the added base will be completely consumed by the reaction.

As a result, the number of moles of acetic acid that remain in solution is:

    n  acetic remaining   =   0.0050  −   0.0040   =    0.0010 moles

The reaction will also produce  0.0040   moles of acetate anions.

This is, then a buffer and the Henderson-Hasselbalch equation is applied to find its pH :

pH  =  p K a  +  log  ( [ conjugate base ]  / [ weak acid ] )

Use the total volume of the solution to find the new concentrations of the acid and of its conjugate base .

V total  =  V acetic  +  V hydroxide

V total  =  25.00 mL  +  40.00 mL  =  65.00 mL

Thus the concentrations will be :

[ CH 3 COOH ]  =  0.0010 moles  / 65.00  ⋅  10 − 3 L  =  0.015385 M

and

[ CH 3 COO − ]  =  0.0040 moles  / 65  ⋅  10 − 3 L  =  0.061538 M

The    p K a     of acetic acid is equal to    4.75

Thus the pH of the solution will be:

pH   =   4.75  +  log ( 0.061538 M  /    0.015385 M )

pH   =   5.35

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