Answer:
a) pH = 4.213
b) % dis = 2 %
Explanation:
Ch3COONa → CH3COO- + Na+
CH3COOH ↔ CH3COO- + H3O+
∴ Ka = 1.8 E-5 = ([ CH3COO- ] * [ H3O+ ]) / [ CH3COOH ]
mass balance:
⇒ <em>C</em> CH3COOH + <em>C</em> CH3COONa = [ CH3COOH ] + [ CH3COO- ]
<em>∴ C </em>CH3COOH = 3.40 mM = 3.4 mmol/mL * ( mol/1000mmol)*(1000mL/L)
∴ <em>C</em> CH3COONa = 1.00 M = 1.00 mol/L = 1.00 mmol/mL
⇒ [ CH3COOH ] = 4.4 - [ CH3COO- ]
charge balance:
⇒ [ H3O+ ] + [ Na+ ] = [ CH3COO- ] + [ OH- ]....is negligible [ OH-], comes from water
⇒ [ CH3COO- ] = [ H3O+ ] + 1.00
⇒ Ka = (( [ H3O+ ] + 1 )* [ H3O+ ]) / ( 3.4 - [ H3O+])) = 1.8 E-5
⇒ [ H3O+ ]² + [ H3O+ ] = 6.12 E-5 - 1.8 E-5 [ H3O+ ]
⇒ [ H3O+ ]² + [ H3O+ ] - 6.12 E-5 = 0
⇒ [ H3O+ ] = 6.12 E-5 M
⇒ pH = - Log [ H3O+ ] = 4.213
b) (% dis)* mol acid = <em>C</em> CH3COOH = 3.4
∴ mol CH3COOH = 500*3.4 = 1700 mmol = 1.7 mol
⇒ % dis = 3.4 / 1.7 = 2 %
Alkina metals all have the similar proteries
The chemical change that involves breaking down substances using electricity is C. Electrolysis.
Answer is: pH of solution is 5,17.
Kb(NH₃) = 1,8·10⁻⁵.
c(NH₄Cl) = 0,084 M = 0,084 mol/L.
Chemical reaction: NH₄⁺ + H₂O → NH₃ + H₃O⁺.
Ka · Kb = 10⁻¹⁴.
Ka(NH₄⁺) = 10⁻¹⁴ ÷ 1,8·10⁻⁵.
Ka(NH₄⁺) = 5,55·10⁻¹⁰.
[H₃O⁺] = [NH₃] = x.
Ka(NH₄⁺) = [H₃O⁺] · [NH₃] ÷ [NH₄⁺].
5,55·10⁻¹⁰ = x² ÷ (0,084 M - x).
Solve quadratic equation: x = [H₃O⁺] = 6,8·10⁻⁶ M.
pH = -log[H₃O⁺].
pH = -log(6,8·10⁻⁶ M) = 5,17.
