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Angelina_Jolie [31]
3 years ago
9

Based on the balanced equation 2C2H2 + 5O2 → 4CO2 + 2H2O calculate the number of excess reagent units remaining when 52 C2H2 mol

ecules and 150 O2 molecules react?
Chemistry
1 answer:
erica [24]3 years ago
5 0

Answer:

20 molecules of oxygen gas remains after the reaction.

Explanation:

2C_2H_2 + 5O_2\rightarrow 4CO_2 + 2H_2O

Molecules of ethyne = 52

Molecules of oxygen gas = 150

According to reaction, 2 molecules of ethyne reacts with 5 molecules of oxygen gas.

Then 52 molecules of ethyne will react with:

\frac{5}{2}\times 52=130 molecules of oxygen gas.

As we can see that we have 150 molecules of oxygen gas, but 52 molecules of ethyne will react with 130 molecules of oxygen gas. So, this means that ethyne is a limiting reagent and oxygen gas is an excessive reagent.

Remaining molecules of recessive reagent = 150 - 130 = 20

20 molecules of oxygen gas remains after the reaction.

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A student sees a change in mass in the lab when mixing two chemicals what is a possible explanation?
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The mixing of two chemicals may result in the production of a gas which is lost to the air. This will reduce the mass of the chemical mixture, because mass is being lost in a gaseous form.

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2 years ago
55 L of a gas at 25oC has its temperature increased to 35oC. What is its new volume?
ladessa [460]

Answer:

Approximately 56.8 liters.

Assumption: this gas is an ideal gas, and this change in temperature is an isobaric process.

Explanation:

Assume that the gas here acts like an ideal gas. Assume that this process is isobaric (in other words, pressure on the gas stays the same.) By Charles's Law, the volume of an ideal gas is proportional to its absolute temperature when its pressure is constant. In other words

\displaystyle V_2 = V_1\cdot \frac{T_2}{T_1},

where

  • V_2 is the final volume,
  • V_1 is the initial volume,
  • T_2 is the final temperature in degrees Kelvins.
  • T_1 is the initial temperature in degrees Kelvins.

Convert the temperatures to degrees Kelvins:

T_1 = \rm 25^{\circ}C = (25 + 273.15)\; K = 298.15\; K.

T_2 = \rm 35^{\circ}C = (35 + 273.15)\; K = 308.15\; K.

Apply Charles's Law to find the new volume of this gas:

\displaystyle V_2 = V_1\cdot \frac{T_2}{T_1} = \rm 55\;L \times \frac{308.15\; K}{298.15\; K} = 56.8\; L.

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One mole of a monatomic ideal gas is subjected to the following sequence of steps: a. Starting at 300 K and 10 atm, the gas expa
Verdich [7]

Answer:

a) Q = 0; W = 0; ΔU = 0; ΔH = 0; ΔS = 0.09 atm.L/K

b) Q = 1250 J; W = 0; ΔU = 1250 J; ΔH = 1250 J; ΔS = -0.0235 atm.L/K

c) Q = 3653.545 J; W = - 3653.545 J; ΔU = 0; ΔH = 0; ΔS = - 3653.545 J

d) Q = - 2080 J; W = 830 J; ΔU = - 1250 J; ΔH = - 2080 J; ΔS = - 5.984 J/K

Explanation:

a) If there is a vacuum, the work is zero, as it is a free expansion, the volume increases, the pressure decreases, the temperature is constant and the internal energy is constant.

∴ n = 1 mole

∴ PV = RTn....ideal gas

∴ P1 = 10 atm

∴ R = 0.082 atm.L/K.mol

∴ T = 300 K = T2

∴ V2 = 3*V1

⇒ W = 0.....expands freely into vacuum

⇒ ΔU = Q = 0....first law

⇒ ΔS = -  nR Ln(P2/P1).....ideal gas

∴ V1*P1/T1 = V2*P2/T2

∴ T1 = T2 = 300 K

⇒ P2 = V1*P1 / V2 = V1*P1 / 3V1 = 10 atm/3 = 3.33 atm

⇒ ΔS = - (1mol)*(0.082 atm.L/K.mol) Ln ( 3.33/10)

⇒ ΔS = 0.09 atm.L/K

∴ ΔH = ΔU + (P2V2 - P1V1) = 0 + 0 = 0

b) heated reversibly at constant volume:

⇒ W = 0 ...at constant volume

∴ T2 = 400 K; T1 = 300 K

∴ V1 = V2

⇒ Q = ΔU = CvΔT....first law

∴ Cv = 12.5 J/K.mol.....monoatomic ideal gas

∴ ΔT = 400 - 300 = 100 K

⇒ Q = ΔU = 12.5 J/mol.K * 100K = 1250 J/mol * 1 mol = 1250 J

∴ ΔH = ΔU + PΔV = ΔU + 0 = 1250 J

∴ ΔS = - nR Ln (P2/P1)

∴ P2/T2 = P1/T1...constant volume

∴ P1 = 3.33 atm

⇒ P2 = P1*T2 / T1 = (3.33 atm)*(400K) / (300K) = 4.44 atm

⇒ ΔS = - (1mol)*(0.082atm.L/K.mol) Ln (4.44/3.33)

⇒ ΔS = - 0.0235 atm.L/K

c) reversibly expanded at constant temperature:

∴ T1 = T2 = 400K

∴ V2 = 3*V1

∴ ΔU = 0...constant temperature

⇒ Q = - W....fisrt law

∴ W = - ∫ PdV..... reversibly expansion

∴ P = nRT/V... ideal gas

⇒ W = - nRT ∫ dV/V

⇒ W = - nRT Ln (V2/V1)

⇒ W = - (1mol)*(8.314 J/K.mol) Ln (3)

⇒ W = - 9.134 J/K *400K = - 3653.545 J

⇒ Q = - W = 3653.545 J

⇒ ΔH = ΔU + P1V1 - P2V2 = 0 + nRT1 - nRT2 = 0 + 0 = 0

∴ ΔS = - nR Ln(P2/P1)

∴ P1 = 4.44 atm

⇒ P2 = V1*P1*T2/ V2*T1 = V1*(4.44atm)*(400K) / (3.V1)*(400K)

⇒ P2 = 4.44atm/3 = 1.48 atm

⇒ ΔS = - (1mol)*(8.314 J/mol.K) Ln (1.48/4.44)

⇒ ΔS = -9.134J/K * 400K = - 3653.545 J

d) reversibly cooled at constant pressure:

∴ T2 = 300 K;  T1 = 400 K

∴ P2 = P1

⇒ Q = ΔH = CpΔT

∴ Cp = 20.8 J/K.mol

∴ ΔT = 300 - 400 = - 100 K

⇒ Q = ΔH = 20.8 J/mol.K * ( -100K) = - 2080 J/mol * 1mol = - 2080 J

⇒ ΔU = nCvΔT = (1mol)*(12.5 J/mol.K)*( - 100K) = -1250 J

⇒ W = ΔU - Q = ΔU - ΔH = -1250 J - ( - 2080 J ) = 830 J

∴ ΔS = ∫ δQ/T = ∫ nCpdT/T

⇒ ΔS = nCp Ln (T2/T1)

⇒ ΔS = (1mol)*(20.8 J/mol.K) Ln (300/400) = - 5.984 J/K

7 0
3 years ago
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