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3 years ago

Successive ionization energy for Cu²+

Chemistry

1 answer:

kogti [31]3 years ago

8 0

Answer:

Here's what I get

Explanation:

The ionization energy (I) is the energy required to remove an electron from an atom in the gaseous phase.

You can remove electrons in succession and measure the energies required as I₁, I₂, I₃, etc.

Thus, the removal of two electrons from Cu gives you Cu²⁺.

I found the ionization energies of Cu and used them to create those of Cu²⁺ (see table and graph below).

The electron configuration of Cu²⁺ is

Cu²⁺: 1s² 2s²2p⁶ 3s²3p⁶ 3d⁹

You can remove the nine 3d electrons and then there is a sudden jump from I₉ to I₁₀ as you break into the filled [Ar] configuration.

Similarly, there is big jump from I₁₇ to I₁₈ as you break into the filled [Ne] configuration.

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Answer: The mass percent of nitrogen gas and hydrogen gas is 91.41 % and 8.59 % respectively.

Explanation:

To calculate the number of moles, we use the equation given by ideal gas equation:

PV = nRT

where,

P = Pressure of the gaseous mixture = 1.00 atm

V = Volume of the gaseous mixture = 24.62 L

n = number of moles of the gaseous mixture = ?

R = Gas constant = $0.0821\text{ L atm }mol^{-1}K^{-1}$

T = Temperature of the gaseous mixture = 300 K

Putting values in above equation, we get:

$1.00atm\times 24.62L=n_{mix}\times 0.0821\text{ L atm }mol^{-1}K^{-1}\times 300K\\\\n_{mix}=\frac{1.00\times 24.62}{0.0821\times 300}=0.9996mol$

We are given:

Total mass of the mixture = 13.22 grams

Let the mass of nitrogen gas be 'x' grams and that of hydrogen gas be '(13.22 - x)' grams

To calculate the number of moles, we use the equation:

$\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}$

For nitrogen gas:

Molar mass of nitrogen gas = 28 g/mol

$\text{Moles of nitrogen gas}=\frac{x}{28}mol$

For hydrogen gas:

Molar mass of hydrogen gas = 2 g/mol

$\text{Moles of hydrogen gas}=\frac{(13.22-x)}{2}mol$

Equating the moles of the individual gases to the moles of mixture:

$0.9996=\frac{x}{28}+\frac{(13.22-x)}{2}\\\\x=12.084g$

To calculate the mass percentage of substance in mixture we use the equation:

$\text{Mass percent of substance}=\frac{\text{Mass of substance}}{\text{Mass of mixture}}\times 100$

Mass of the mixture = 13.22 g

For nitrogen gas:

Mass of nitrogen gas = x = 12.084 g

Putting values in above equation, we get:

$\text{Mass percent of nitrogen gas}=\frac{12.084g}{13.22g}\times 100=91.41\%$

For hydrogen gas:

Mass of hydrogen gas = (13.22 - x) = (13.22 - 12.084) g = 1.136 g

Putting values in above equation, we get:

$\text{Mass percent of hydrogen gas}=\frac{1.136g}{13.22g}\times 100=8.59\%$

Hence, the mass percent of nitrogen gas and hydrogen gas is 91.41 % and 8.59 % respectively.

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Successive ionization energy for Cu²+​

Successive ionization energy for Cu²+