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PIT_PIT [208]
3 years ago
9

Which of the following (with specific heat capacity provided) would show the smallest temperature change upon gaining 200.0 J of

heat? a. 50.0 g Fe, CFe = 0.449 J/g°C b. 50.0 g water, Cwater = 4.18 J/g°C c. 25.0 g Pb, CPb = 0.128 J/g°C d. 25.0 g Ag, CAg=0.235 J/g°C e. 25.0 g granite, Cgranite = 0.79 J/g°C
Chemistry
1 answer:
Brut [27]3 years ago
5 0

<u>Answer:</u> The smallest temperature change is shown by water.

<u>Explanation:</u>

To calculate the heat absorbed or released, we use the equation:

q=mC\times \Delta T      ......(1)

where,

q = heat absorbed = 200.0 J

m = mass of the substance

C = specific heat of substance

\Delta T = change in temperature

As, the same amount of heat is getting absorbed in all the cases. So, the change in temperature will depend on the product of mass and specific heat.

For the given options:

  • <u>Option a:</u>  50.0 g Fe, C_{Fe}=0.449J/g^oC

We are given:

m=50.0g\\C_{Fe}=0.449J/g^oC

Putting values in equation 1, we get:

200.0J=50.0g\times 0.449J/g^oC\times \Delta T\\\\\Delta T=\frac{200}{50\times 0.449}=8.99^oC

Change in temperature = 8.99°C

  • <u>Option b:</u>  50.0 g water, C_{water}=4.18J/g^oC

We are given:

m=50.0g\\C_{water}=4.18J/g^oC

Putting values in equation 1, we get:

200.0J=50.0g\times 4.18J/g^oC\times \Delta T\\\\\Delta T=\frac{200}{50\times 4.18}=0.96^oC

Change in temperature = 0.96°C

  • <u>Option b:</u>  25.0 g Pb, C_{Pb}=0.128J/g^oC

We are given:

m=50.0g\\C_{Pb}=0.128J/g^oC

Putting values in equation 1, we get:

200.0J=25.0g\times 0.128J/g^oC\times \Delta T\\\\\Delta T=\frac{200}{25\times 0.128}=62.5^oC

Change in temperature = 62.5°C

  • <u>Option d:</u>  25.0 g Ag, C_{Ag}=0.235J/g^oC

We are given:

m=25.0g\\C_{Ag}=0.235J/g^oC

Putting values in equation 1, we get:

200.0J=25.0g\times 0.235J/g^oC\times \Delta T\\\\\Delta T=\frac{200}{25\times 0.235}=34.04^oC

Change in temperature = 34.04°C

  • <u>Option e:</u>  25.0 g granite, C_{granite}=0.79J/g^oC

We are given:

m=25.0g\\C_{Fe}=0.79J/g^oC

Putting values in equation 1, we get:

200.0J=25.0g\times 0.79J/g^oC\times \Delta T\\\\\Delta T=\frac{200}{25\times 0.79}=10.13^oC

Change in temperature = 10.13°C

Hence, the smallest temperature change is shown by water.

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Rate of reaction : It is defined as the change in the concentration of any one of the reactants or products per unit time.

The expression for rate of reaction will be :

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\text{Rate of formation of D}=+\frac{1}{d}\frac{d[D]}{dt}

Rate=-\frac{1}{a}\frac{d[A]}{dt}=-\frac{1}{b}\frac{d[B]}{dt}=+\frac{1}{c}\frac{d[C]}{dt}=+\frac{1}{d}\frac{d[D]}{dt}

From this we conclude that,

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a, b, c and d are the stoichiometric coefficient of A, B, C and D respectively.

The negative sign along with the reactant terms is used simply to show that the concentration of the reactant is decreasing and positive sign along with the product terms is used simply to show that the concentration of the product is increasing.

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