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PIT_PIT [208]
3 years ago
9

Which of the following (with specific heat capacity provided) would show the smallest temperature change upon gaining 200.0 J of

heat? a. 50.0 g Fe, CFe = 0.449 J/g°C b. 50.0 g water, Cwater = 4.18 J/g°C c. 25.0 g Pb, CPb = 0.128 J/g°C d. 25.0 g Ag, CAg=0.235 J/g°C e. 25.0 g granite, Cgranite = 0.79 J/g°C
Chemistry
1 answer:
Brut [27]3 years ago
5 0

<u>Answer:</u> The smallest temperature change is shown by water.

<u>Explanation:</u>

To calculate the heat absorbed or released, we use the equation:

q=mC\times \Delta T      ......(1)

where,

q = heat absorbed = 200.0 J

m = mass of the substance

C = specific heat of substance

\Delta T = change in temperature

As, the same amount of heat is getting absorbed in all the cases. So, the change in temperature will depend on the product of mass and specific heat.

For the given options:

  • <u>Option a:</u>  50.0 g Fe, C_{Fe}=0.449J/g^oC

We are given:

m=50.0g\\C_{Fe}=0.449J/g^oC

Putting values in equation 1, we get:

200.0J=50.0g\times 0.449J/g^oC\times \Delta T\\\\\Delta T=\frac{200}{50\times 0.449}=8.99^oC

Change in temperature = 8.99°C

  • <u>Option b:</u>  50.0 g water, C_{water}=4.18J/g^oC

We are given:

m=50.0g\\C_{water}=4.18J/g^oC

Putting values in equation 1, we get:

200.0J=50.0g\times 4.18J/g^oC\times \Delta T\\\\\Delta T=\frac{200}{50\times 4.18}=0.96^oC

Change in temperature = 0.96°C

  • <u>Option b:</u>  25.0 g Pb, C_{Pb}=0.128J/g^oC

We are given:

m=50.0g\\C_{Pb}=0.128J/g^oC

Putting values in equation 1, we get:

200.0J=25.0g\times 0.128J/g^oC\times \Delta T\\\\\Delta T=\frac{200}{25\times 0.128}=62.5^oC

Change in temperature = 62.5°C

  • <u>Option d:</u>  25.0 g Ag, C_{Ag}=0.235J/g^oC

We are given:

m=25.0g\\C_{Ag}=0.235J/g^oC

Putting values in equation 1, we get:

200.0J=25.0g\times 0.235J/g^oC\times \Delta T\\\\\Delta T=\frac{200}{25\times 0.235}=34.04^oC

Change in temperature = 34.04°C

  • <u>Option e:</u>  25.0 g granite, C_{granite}=0.79J/g^oC

We are given:

m=25.0g\\C_{Fe}=0.79J/g^oC

Putting values in equation 1, we get:

200.0J=25.0g\times 0.79J/g^oC\times \Delta T\\\\\Delta T=\frac{200}{25\times 0.79}=10.13^oC

Change in temperature = 10.13°C

Hence, the smallest temperature change is shown by water.

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The number of particles is calculated as:

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A) NaCl          ionic            ions Na⁺ and Cl⁻        1.0            1.0 × 1 × 2 = 2

B) NaCl          ionic            ions Na⁺ anc Cl⁻        0.5           0.5 × 1 × 2 = 1

C) Glucose    covalent     molecules                   0.5          0.5 × 1 × 1 = 0.5

D) Glucose    covalent     molecules                   1.0           1.0 × 1  × 1 = 1

Therefore, the rank in increasing number of particles is for the list of solutions given is: C < B = D < A, which means that the solution expected to contain the greatest number of solute particles is the solution A) 1 L of 1.0 M NaCl.

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A student was asked to name an element that reacts like chlorine (Cl). Which element should the student name?
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Calculate the amount of heat in kJ that is required to heat 25.0 g of ice from -25 °C to 105 °C in a closed vessel and sketch a
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Answer:

The total amount of heat required for the process is 76.86 KJ

Explanation:

We can divide the process in 5 parts, in which we can calcule each amount of heat required (see attached Heating curve):

(1) Ice is heated from -25ºC to 0ºC. We can calculate the heat of this part of the process as follows. Note that we must convert J in KJ (1 KJ= 1000 J).

Heat (1) = mass ice x Specific heat ice x (Final temperature - Initial Temperature)

Heat (1) =25 g x 2.11 J/g.ºC x \frac{1 KJ}{1000 J} x (0ºC-(-25º)

Heat (1) = 1.32 KJ

(2) Ice melts at ºC (it becomes liquid water). This is heating at constant temperature (ºC), so we use the melting enthalphy (ΔHmelt) and we must use the molecular weight of water (1 mol H₂O = 18 g):

Heat (2) = mass ice x ΔHmelt

Heat (2)= 25 g  x  \frac{6.01KJ} {1 mol H2O} x \frac{1 mol H2O}{18 g}

Heat (2)= 8.35 KJ

(3) Liquid water is heated from 0ºC to 100 ºC:

Heat (3)= mass liquid water x Specific heat water x (Final T - Initial T)

Heat (3)= 25 g x 4.18 J/gºC x 1 KJ/1000 J x (100ºC - 0ºC)

Heat (3)= 10.45 KJ

(4) Liquid water evaporates at 100ºC (it becomes water vapor). This is a process at constant temperature (100ºC), and we use boiling enthalpy:

Heat (4)= mass water x ΔH boiling

Heat (4)= 25 g x \frac{40.67 KJ}{mol H20} x \frac{1 mol H20}{18 g}

Heat (4)= 56.49 KJ

(5) Water vapor is heated from 100ºC to 105ºC. We use the specific capacity of water vapor:

Heat (5)= mass water vapor x Specific capacity vapor x (Final T - Initial T)

Heat (5)= 25 g x 2.00 J/g ºC x 1 KJ/1000 J x (105ºC - 100ºC)

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Total heat= Heat(1) + (Heat(2) + Heat(3) + Heat(4) + Heat(5)

Total heat= 1.32 KJ + 8.35 KJ + 10.45 KJ + 56.49 KJ + 0.25 KJ

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