Answer:
2.8 * 10^(-6) / 1.4 * 10^(-2)=
2* 10^(-8)
The Henderson-Hasselbalch approximation is for conjugate acid-base pairs in a buffered solution. We're going to call HA a weak acid, and A- its conjugate base. The equation is as follows:
pH = pKa + log([base]/[acid]), where the brackets imply concentrations
Plugging in our symbols and the pKa value, the equation becomes:
pH = 4.874 + log([A-]/[HA])
Methane is the compound CH4, and burning it uses the reaction:
CH4 + O2 -> CO2 + H2O, which is rather exothermic. To find the heat released by burning a certain amount of the substance, you should look at the bond enthalpy of each compound, and then compare the values before and after the reaction. In methane, there are 4 C-H bonds, which have bond energy of 416 kj/mol, resulting in a total bond energy of 1664 kj/mol. O2 is 494 kj/mol. Therefore we have a total of 2080 kj/mol on the left side. On the right side we have CO2, which has 2 C=O bonds, each at 799 kj/mol each, resulting in 1598 kj/mol, and H2O has 2 O-H bonds, at 459kj/mol each, resulting in a total of 2516 kj/mol on the right hand side. Now, this may be confusing because the left hand side seems to have less heat than the right, but you just need to remember: making minus breaking, which results in a total change of 436kj/mol heat evolved.
Now it is a simple matter of find the mols of CH4 reacted, using n=m/mr.
n = 9.5/16.042 = 0.592195 mol
Therefore, if we reacted 0.592195 mol, and we produced 436 kj for one mol, the total amount of energy evolved was 436*<span>0.592195 kj, or 258.197 kj.</span>
