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Sonja [21]
3 years ago
13

Potassium hydroxide is classified as an arrhenius base because koh contains

Chemistry
1 answer:
mixas84 [53]3 years ago
8 0

Answer: hydroxide ions

Explanation:

According to the Arrhenius concept, an acid is a substance that ionizes in the water to give hydronium ion or hydrogen ion  and a bases is a substance that ionizes in the water to give hydroxide ion .

According to the Bronsted Lowry conjugate acid-base theory, an acid is defined as a substance which donates protons and a base is defined as a substance which accepts protons.

According to the Lewis concept, an acid is defined as a substance that accepts electron pairs and base is defined as a substance which donates electron pairs.

As KOH can give hydroxide ions on dissociation , it is considered as arrhenius base.

KOH\rightarrow K^++OH^-

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For the reaction A + B + C → D + E, the initial reaction rate was measured for various initial concentrations of reactants. The
Alik [6]

Answer : The rate for trial 5 will be 4.25\times 10^{-2}Ms^{-1}

Explanation :

Rate law is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.

For the given chemical equation:

A+B+C\rightarrow D+E

Rate law expression for the reaction:

\text{Rate}=k[A]^a[B]^b[C]^c

where,

a = order with respect to A

b = order with respect to B

c = order with respect to C

Expression for rate law for first observation:

6.0\times 10^{-4}=k(0.20)^a(0.20)^b(0.20)^c ....(1)

Expression for rate law for second observation:

1.8\times 10^{-3}=k(0.20)^a(0.20)^b(0.60)^c ....(2)

Expression for rate law for third observation:

2.4\times 10^{-3}=k(0.40)^a(0.20)^b(0.20)^c ....(3)

Expression for rate law for fourth observation:

2.4\times 10^{-3}=k(0.40)^a(0.40)^b(0.20)^c ....(4)

Dividing 1 from 2, we get:

\frac{1.8\times 10^{-3}}{6.0\times 10^{-4}}=\frac{k(0.20)^a(0.20)^b(0.60)^c}{k(0.20)^a(0.20)^b(0.20)^c}\\\\3=3^c\\c=1

Dividing 1 from 3, we get:

\frac{2.4\times 10^{-3}}{6.0\times 10^{-4}}=\frac{k(0.40)^a(0.20)^b(0.20)^c}{k(0.20)^a(0.20)^b(0.20)^c}\\\\4=2^a\\a=2

Dividing 3 from 4, we get:

\frac{2.4\times 10^{-3}}{2.4\times 10^{-3}}=\frac{k(0.40)^a(0.40)^b(0.20)^c}{k(0.40)^a(0.20)^b(0.20)^c}\\\\1=2^b\\b=0

Thus, the rate law becomes:

\text{Rate}=k[A]^2[B]^0[C]^1

Now, calculating the value of 'k' by using any expression.

Putting values in equation 1, we get:

6.0\times 10^{-4}=k(0.20)^2(0.20)^0(0.20)^1

k=7.5\times 10^{-2}M^{-2}s^{-1}

Thus, the value of the rate constant 'k' for this reaction is 7.5\times 10^{-2}M^{-2}s^{-1}

Now we have to calculate the rate for trial 5 that starts with 0.90 M of reagent A, 0.60 M of reagents B and 0.70 M of reagent C.

\text{Rate}=k[A]^2[B]^0[C]^1

\text{Rate}=(7.5\times 10^{-2})\times (0.90)^2(0.60)^0(0.70)^1

\text{Rate}=4.25\times 10^{-2}Ms^{-1}

Therefore, the rate for trial 5 will be 4.25\times 10^{-2}Ms^{-1}

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