Aldehydes are usually more reactive<span> toward nucleophilic substitutions </span>than<span> ketones because of both steric and electronic effects. In aldehydes, the relatively small hydrogen atom is attached to one side of the carbonyl group, while a larger R group is affixed to the other side.</span>
Answer:
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The answer is iii) decreasing the pressure of the system. When the pressure is decreased, the equilibrium will shift to the right because it has 12 moles of gas which is greater than the number of moles of gas on the left side, which is 6 moles. Equilibrium shifting to the side that exerts greater pressure is favored to offset the decrease in pressure.
