Answer:
Initially
of nitrogen dioxide were in the container .
Explanation:
Volume of the container at low pressure and at room temperature =
Number of moles in the container = 
After more addition of nitrogen gas at the same pressure and temperature.
Volume of the container after addition = 
Number of moles in the container after addition=
Applying Avogadro's law:
(at constant pressure and temperature)



Initially
of nitrogen dioxide were in the container .
What do you mean by that? Can you explain further?
Answer:

Explanation:
Hello,
In this case, since the undergoing chemical reaction is:

The corresponding moles of carbon dioxide occupying 40.0 mL (0.0400 L) are computed by using the ideal gas equation at 273.15 K and 1.00 atm (STP) as follows:

Then, since the mole ratio between carbon dioxide and calcium carbonate is 1:1 and the molar mass of the reactant is 100 g/mol, the mass that yields such volume turns out:

Regards.
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