Answer:
ΔH = -470.4kJ
Explanation:
It is possible to sum 2 or more reactions to obtain the ΔH of the reaction you want to study (Hess's law). Using the reactions:
1. CaC2(s) + 2H2O(l) → C2H2(g) + Ca(OH)2(s)ΔH = −414kJ
2. 6C2H2(g) + 3CO2(g) + 4H2O(g) → 5CH2CHCO2H(g)ΔH = 132kJ
6 times the reaction 1.
6CaC2(s) + 12H2O(l) → 6C2H2(g) + 6Ca(OH)2(s)ΔH = −414kJ*6 = -2484kJ
This reaction + 2:
6CaC2(s) + 3CO2(g) + 16H2O(l) → + 6Ca(OH)2(s) + 5CH2CHCO2H(g) ΔH = -2484kJ + 132kJ = -2352kJ
As we want to calculate the net change enthalpy in the formation of just 1 mole of acrylic acid we need to divide this last reaction in 5:
6/5CaC2(s) + 3/5CO2(g) + 16/5H2O(l) → + 6/5Ca(OH)2(s) + CH2CHCO2H(g) ΔH = -2352kJ / 5
<h3>ΔH = -470.4kJ</h3>
Answer:
Correct option is B)
According to de-Broglie,
λ=mvh=6.023×10232×5×104cm/sec6.62×10−27ergsec=4×10−8cm=4Ao
4% mass / volume :
4 g ---------> 100 mL
1.2 g ------- ? mL
V = 1.2 * 100 / 4
V = 120 / 4
V = 30 mL
hope this helps!
