Answer:
The correct order of increasing reactivity toward nucleophilic acyl substitution is E < D < C < A < F < B.
Explanation:
The stability of the leaving group best determines the manner of reactivity of carboxylates to nucleophilic substitution after the substitution of the nucleophile to the leaving group. The leaving group should, therefore, be protonated with hydrogen ion in the solution to form a stable molecule. From the given list: The leaving group for A, Ethyl thioacetate will be ethanethiol. For B, Acetyl chloride will be Hydrochloric acid. For C, Sodium acetate will be Sodium Hydroxide. For D, Ethyl acetate will be Ethanol. For E, Acetamide will be Ammonia, and for F, Acetic anhydride will be Ethanoic acid. The reactivity of the substitution reaction is dependent on the stability of these leaving groups. The stability of these leaving groups depends on their pKa, and the more the pKa, the lesser the acidity of the leaving group, and the lower the reactivity. Therefore, considering their pKa: A is 8.5, B is -7, C is 13.8, D is 15.9, E is 36, and F is 4.8. When we rearrange this pKa in descending order, we have E, D. C, A, F, B. Which is also the increased reactivity of the nucleophilic acyl substitution.
Well if too much weathering occurs, it might break off parts of the cliff and be dangerous to humans, or animals.
Answer:
Down below
Explanation:
The following uses nickel(II) chloride
2AgNO3(aq) + NiCl2(aq) ==> Ni(NO3)2(aq) + 2AgCl(s) Molecular
Answers-in-bold:
There are two common temperature scales. On the Fahrenheit scale, water freezes at 32 degrees. The Celsius scale divides the interval between the freezing and boiling points of water into 100 degrees.