Answer:
Result of the formation of positive and negative ions.
First, we need to calculate moles of hydrazoic acid NH3:
moles NH3 = molarity * volume
= 0.15 m * 0.025 L
= 0.00375 moles
moles NaOH = molarity * volume
= 0.15 m * 0.015 L
= 0.00225 moles
after that we shoul get the total volume = 0.025L + 0.015L
= 0.04 L
So we can get the concentration of NH3 & NaOH by:
∴[NH3] = moles NH3 / total volume
= 0.00375 moles / 0.04 L
= 0.09375 M
∴[NaOH] = moles NaOH / total volume
= 0.00225 moles / 0.04 L
= 0.05625 M
then, when we have the value of Ka of NH3 so we can get the Pka value from:
Pka = -㏒Ka
= - ㏒ 1.9 x10^-5
= 4.7
finally, by using H-H equation we can get PH:
PH = Pka + ㏒[salt/ basic]
PH = 4.7 +㏒[0.05625/0.09375]
∴ PH = 4.48
Answer:
Pu-239
Explanation:
Beta decay moves the element which undergoes the decay one place to the right in the periodic table since to conserve charge and being beta radiations an electron we convert a neutron into a proton and an electron. In neutron capture we increase the atomic mas by one unit. We that in mind, lets solve the question:
U-238 + ₁⁰ n ⇒ U-239 ⇒ Np -239 + ₋₁⁰β ⇒ Pu-239 + ₋₁⁰β
Answer:
a=28600J; b=90.6 J/K; c=402 torr
Explanation:
(a) considering the data given
Vapour pressure P1 =0 at Temperature T1 = 42.43˚C,
Vapour pressure P2 = 273.15 at Temperature T2= 315.58 K)
Using the Clausius-Clapeyron Equation
ln (P2/P1) = (ΔH/R)(1/T2 - 1/T1)
In 760/140 = ΔH/8.314 J/mol/K × (1/315.58K -- 1/273.15K)
ΔH vap= +28.6 kJ/mol or 28600J
(b) using the Equation ΔG°=ΔH° - TΔS to solve forΔS.
Since ΔG at boiling point is zero,
ΔS =(ΔH°vap/Τb)
ΔS = 28600 J/315.58 K
= 90.6 J/K
(c) using ln (P2/P1) = (ΔH/R)(1/T2 - 1/T1)
ln P298 K/1 atm = 28600 J/8.314 J/mol/K × (1/298.15K - 1/315.58K)
P298 K = 0.529 atm
= 402 torr
