Linoleic acid is a polyunsaturated fatty acid found, in ester form, in many fats and oils. Its doubly allylic hydrogens are part
icularly susceptible to abstraction by radicals, a process that can lead to the oxidative degradation of the fat or oil. The radical formed by abstraction of one of the doubly allylic hydrogens is an allylic radical that has three resonance structures. Complete one of these resonance structures by dragging bonds and electrons to their appropriate positions.
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Answer:
pH ≅ 4.80
Explanation:
Given that:
the volume of HN₃ = 25 mL = 0.025 L
Molarity of HN₃ = 0.150 M
number of moles of HN₃ = 0.025 × 0.150
number of moles of HN₃ = 0.00375 mol
Molarity of NaOH = 0.150 M
the volume of NaOH = 13.3 mL = 0.0133
number of moles of NaOH = 0.0133× 0.150
number of moles of NaOH = 0.001995 mol
The chemical equation for the reaction of this process can be written as:
1 mole of hydrazoic acid react with 1 mole of hydroxide to give nitride ion and water
thus the new number of moles of HN₃ = 0.00375 - 0.001995 = 0.001755 mol
Total volume used in the reaction = 0.025 + 0.0133 = 0.0383 L
Concentration of =
= 0.0458 M
Concentration of =
= 0.0521 M
GIven that :
Ka =
Thus; it's pKa = 4.72
pH ≅ 4.80