The columns of the periodic table, also referred to as "groups" contain elements with similar reactive properties, due to these elements having a similar configuration of electrons in their outer shell.
It has to be understood that 2 moles of oxygen are there in each mole of PbO2. Then it has to be calculated for 2 moles of oxygen.
Amount of oxygen = 2 * 5.43 moles
= 10.86 moles
Now it is also a fact that each mole of H2O contains 1 mole of oxygen. Then it can be easily concluded that 10.86 moles of water will be produced. I hope the procedure is clear enough for you to understand.
They can all by seperrated or replicated.