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Ierofanga [76]
3 years ago
11

Write chemical equations and corresponding equilibrium expressions for each of the two ionization steps of carbonic acid. Part A

Write chemical equations for first ionization step of carbonic acid. Express your answer as a chemical equation. Identify all of the phases in your answer. nothing Request Answer Part B Complete previous part(s) Part C Write chemical equations for second ionization step of carbonic acid. Express your answer as a chemical equation. Identify all of the phases in your answer. nothing
Chemistry
1 answer:
lesantik [10]3 years ago
6 0

<u>Answer:</u> The chemical equations and equilibrium constant expression for each ionization steps is written below.

<u>Explanation:</u>

The chemical formula of carbonic acid is H_2CO_3. It is a diprotic weak acid which means that it will release two hydrogen ions when dissolved in water

The chemical equation for the first dissociation of carbonic acid follows:

               H_2CO_3(aq.)\rightleftharpoons H^+(aq.)+HCO_3^-(aq.)

The expression of first equilibrium constant equation follows:

Ka_1=\frac{[H^+][HCO_3^{-}]}{[H_2CO_3]}

The chemical equation for the second dissociation of carbonic acid follows:

               HCO_3^-(aq.)\rightarrow H^+(aq.)+CO_3^{2-}(aq.)

The expression of second equilibrium constant equation follows:

Ka_2=\frac{[H^+][CO_3^{2-}]}{[HCO_3^-]}

Hence, the chemical equations and equilibrium constant expression for each ionization steps is written above.

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Complete and balance the chemical equations for the precipitation reactions, if any, between the following pairs of reactants, a
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Explanation:

a. Pb(NO_3)_2(aq) + Na_2SO_4(aq) → ?

Pb(NO_3)_2(aq) + Na_2SO_4(aq)\rightarrow PbSO_4(s)+2NaNO_3(aq)

Pb(NO_3)_2(aq)\rightarrow Pb^{2+}(aq)+2NO_3^{-}(aq)

Na_2SO_4(aq)\rightarrow 2Na^++SO_4^{2-}(aq)

Pb^{2+}(aq)+2NO_3^{-}(aq)+2Na^++SO_4^{2-}(aq)\rightarrow PbSO_4(s)+2Na^++2NO_3^{-}(aq)

Removing common ions from both sides, we get the net ionic equation:

Pb^{2+}(aq)+SO_4^{2-}(aq)\rightarrow PbSO_4(s)

b. NiCl_2(aq) + NH_4NO_3(aq) →

NiCl_2(aq) + NH4NO_3(aq) \rightarrow Ni(NO_3)_2+NH_4Cl(aq)

No precipitation is occuring.

c. Fe_Cl2(aq) + Na_2S(aq) →

FeCl_2(aq) + Na_2S(aq)\rightarrow FeS(s)+2NaCl(aq)

FeCl_2(aq)\rightarrow Fe^{2+}(aq)+2Cl^{-}(aq)

Na_2S(aq)\rightarrow 2Na^++S{2-}(aq)

Fe^{2+}(aq)+2Cl^{-}(aq)+2Na^++S^{2-}(aq)\rightarrow FeS(s)+2Na^++2Cl^{-}(aq)

Removing common ions from both sides, we get the net ionic equation:

Fe^{2+}(aq)+S^{2-}(aq)\rightarrow FeS(s)

d.MgSO_4(aq) + BaCl_2(aq) →

MgSO4(aq) + BaCl2(aq)\rightarrow BaSO_4(s)+MgCl_2

MgSO_4(aq)\rightarrow Mg^{2+}(aq)+SO_4^{2-}(aq)

BaCl_2(aq)\rightarrow Ba^{2+}+2Cl^{-}(aq)

Mg^{2+}(aq)+SO_4^{2-}(aq)+Ba^{2+}+2Cl^{-}(aq)(aq)\rightarrow BaSO_4(s)+Mg^{2+}(aq)+2Cl^{-}(aq)

Removing common ions from both sides, we get the net ionic equation:

Ba^{2+}(aq)+SO_4^{2-}(aq)\rightarrow BaSO_4(s)

5 0
3 years ago
If the reaction N2 (g) + 3 H2 (g) --&gt; 2 NH3 (g) has the concentrations 1.1 M for nitrogen, 0.75 M for hydrogen and 0.25 M fo
Luba_88 [7]

<u>Answer:</u> The value of K_c is 0.136 and is reactant favored.

<u>Explanation:</u>

Equilibrium constant in terms of concentration is defined as the ratio of concentration of products to the concentration of reactants each raised to the power their stoichiometric ratios. It is expressed as K_{c}

For the chemical reaction between carbon monoxide and hydrogen follows the equation:

N_2(g)+3H_2(g)\rightleftharpoons 2NH_3(g)

The expression for the K_{c} is given as:

K_{c}=\frac{[NH_3]^2}{[N_2][H_2]^3}

We are given:

[NH_3]=0.25M

[H_2]=0.75M

[N_2]=1.1M

Putting values in above equation, we get:

K_c=\frac{(0.25)^2}{1.1\times (0.75)^3}

K_c=0.135

There are 3 conditions:

  • When K_{c}>1; the reaction is product favored.
  • When K_{c}; the reaction is reactant favored.
  • When K_{c}=1; the reaction is in equilibrium.

For the given reaction, the value of K_c is less than 1. Thus, the reaction is reactant favored.

Hence, the value of K_c is 0.136 and is reactant favored.

4 0
3 years ago
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