A) because spontaneous means in an instant
(2) U-238 is the radioisotope used in dating geological formations. Uranium-238 has a half-life of 4.46 billion years, which makes it suitable to date such old formations.
The other options do not have such long durabilities and half-lives.
Mass is always conserved in a physical change. Energy may be released or absorbed when a substance changes from one physical state to another. In a chemical change, a chemical reaction yields a completely new substance. A substance's particles are changed during a chemical reaction.
The reaction N2O4 (g) <--> 2NO2 (g) is endothermic, meaning that it consumes heat to move towards formation of the products.
According to Le Chatelier's Principle, therefore, if heat is added, more product (NO2) will be produced, and equilibrium would shift towards the right side. This is choice 3.