Answer:
[A]²
Explanation:
Since the formation is independent of D, D is 0 order.
Since a quadruples when it is doubled it can be written as
2A^X= 4
To find the unknown power we can assume A= 1 to make the math simple. So When a = 2 (Because you doubled it) raised to X power it will equal 4
so the unknown power is 2
Making the rate law
[a]²[b]⁰
or simply just
[A]²
Answer: New pressure inside the flask would be 148.8 kPa.
Explanation: The combined gas law equation is given by:

As the flask is a closed flask, so the volume remains constant. Temperature is constant also.
So, the relation between pressure and number of moles becomes



- Final conditions: When additional 3 puffs of air is added

Putting the values, in above equation, we get

It would be: 1s2, 2s2, 2p4