Answer:
see explanation below
Explanation:
First to all, this is a redox reaction, and the reaction taking place is the following:
2KMnO4 + 3H2SO4 + 5H2O2 -----> 2MnSO4 + K2SO4 + 8H2O + 5O2
According to this reaction, we can see that the mole ratio between the peroxide and the permangante is 5:2. Therefore, if the titration required 21.3 mL to reach the equivalence point, then, the moles would be:
MhVh = MpVp
h would be the hydrogen peroxide, and p the permanganate.
But like it was stated before, the mole ratio is 5:2 so:
5MhVh = 2MpVp
Replacing moles:
5nh = 2MpVp
Now, we just have to replace the given data:
nh = 2MpVp/5
nh = 2 * 1.68 * 0.0213 / 5
nh = 0.0143 moles
Now to get the mass, we just need the molecular mass of the peroxide:
MM = 2*1 + 2*16 = 34 g/mol
Finally the mass:
m = 0.0143 * 34
m = 0.4862 g
This problem is describing the state two gases have when separated and together as shown on the attached picture. First of all, diagram 1 shows how they are separated in two containers with apparently equal volumes, whereas diagram 2 shows the removal of the barrier so that they get mixed together.
In this case, we can analyze that each gas has its own pressure and due to the removal of the barrier, both pressure and volume undergo a change. Thus, we can infer that the final volume is doubled with respected to the initial one for each gas, causing the pressure of each gas to be halved and the total pressure the half of the added ones, in agreement to the Boyle's law (inversely proportional relationship between pressure and temperature).
Therefore, the correct choice is:
C. The partial pressure of each gas in the mixture is half its initial pressure; the final total pressure is half the sum of the initial pressures of the two gases.
Learn more:
For apex the answer is no solution
- From the general law of gases: PV = nRT,
where P is the pressure (atm),
V is the volume (L),
n is the number of moles,
R is the general gas constant (8.314 L.atm/mol.K),
T is the temperature in Kelvin
- at constant volume of the gas: P1T2 = P2T1
P1 = 3.20 atm, T1 = 300 K, T2 = 290 K, P2 = ??
(3.20 atm)(290 K) = P2(300 K)
P2 = (3.20 atm)(290 K)/ (300 K) = 3.093 atm
