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3 years ago

12

A second reaction mixture was made up in the following way:

1 answer:

Leya [2.2K]3 years ago

6 0

A. We can calculate the initial concentrations of each by the formula:

initial concentration ci = initial volume * initial concentration / total mixture volume

where,

total mixture volume = 10 mL + 20 mL + 10 mL + 10 mL = 50 mL

ci (acetone) = 10 mL * 4.0 M / 50 mL = 0.8 M

ci (H+) = 20 mL * 1.0 M / 50 mL = 0.4 M (note: there is only 1 H+ per 1 HCl)

ci (I2) = 10 mL * 0.0050 M / 50 mL = 0.001 M

B. The rate of reaction is determined to be complete when all of I2 is consumed. This is signified by complete disappearance of I2 color in the solution. The rate therefore is:

rate of reaction = 0.001 M / 120 seconds

rate of reaction = 8.33 x 10^-6 M / s

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According to Hund's rule of maximum spin multiplicity, how many singly-occupied orbitals are there in the valence shells of the

leva [86]

Answer:

A) carbon - 2

B) cobalt - 3

C) sulfur - 2

D) fluorine - 1

E) titanium - 2

F) germanium - 2

Explanation:

Hund's rule of maximum multiplicity:-

Firstly, every orbital which is present in the sublevel is singly occupied and then the orbital is doubly occupied.

(A) Carbon.

The electronic configuration is -

$1s^22s^22p^2$

Thus, 2s orbital is fully filled and p orbital can singly filled 3 electrons. Thus, Carbon has 2 singly occupied orbitals.

(B) Cobalt.

The electronic configuration is -

$1s^22s^22p^63s^23p^63d^{7}4s^2$

Thus, 4s orbital is fully filled and d orbital can singly filled 5 electrons. Thus, 4 electrons will be paired in 2 orbitals and 3 orbitals will be singly filled in cobalt.

(C) Sulfur.

The electronic configuration is -

$1s^22s^22p^63s^23p^4$

Thus, 3s orbital is fully filled and p orbital can singly filled 3 electrons. Thus, 2 electrons will be paired in 1 orbital and 2 orbitals will be singly filled in sulfur.

D) fluorine

The electronic configuration is -

$1s^22s^22p^5$

Thus, 2s orbital is fully filled and p orbital can singly filled 3 electrons. Thus, 4 electrons will be paired in 2 orbitals and 1 orbital will be singly filled in fluorine.

E) Titanium

The electronic configuration is -

$1s^22s^22p^63s^23p^63d^{2}4s^2$

Thus, 4s orbital is fully filled and d orbital can singly filled 5 electrons. Thus, 2 orbitals will be singly filled in titanium.

F) Germanium

The electronic configuration is -

$1s^22s^22p^63s^23p^63d^{10}4s^24p^2$

Thus, 4s, 3d orbitals are fully filled and p orbital can singly filled 3 electrons. Thus, Germanium has 2 singly occupied orbitals.

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Evgesh-ka [11]

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Svetllana [295]

Answer:

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Explanation:

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