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kompoz [17]
3 years ago
8

What concentrations of acetic acid (pKa = 4.76) and acetate would be required to prepare a 0.15 M buffer solution at pH 5.0? Not

e that the concentration and/or pH value may differ from that in the first question. STRATEGY 1. Rearrange the Henderson-Hasselbalch equation to solve for the ratio of base (acetate) to acid (acetic acid), [A–]/[HA]. 2. Use the mole fraction of acetate to calculate the concentration of acetate. 3. Calculate the concentration of acetic acid. Step 1: Rearrange the Henderson Hasselbalch equation to solve for (A-)/(HA) if the solution is at ph 5.0
Chemistry
1 answer:
Leni [432]3 years ago
7 0

Answer:

Acetic acid 0,055M and acetate 0,095M.

Explanation:

It is possible to prepare a 0,15M buffer of acetic acid/acetate at pH 5,0 using Henderson-Hasselblach formula, thus:

pH = pka + log₁₀ [A⁻]/[HA] <em>-Where A⁻ is acetate ion and HA is acetic acid-</em>

Replacing:

5,0 = 4,76 + log₁₀ [A⁻]/[HA]

<em>1,7378 =  [A⁻]/[HA] </em><em>(1)</em>

As concentration of buffer is 0,15M, it is possible to write:

<em>[A⁻] + [HA] = 0,15M </em><em>(2)</em>

Replacing (1) in (2):

1,7378[HA] + [HA] = 0,15M

2,7378[HA] = 0,15M

[HA] = 0,055M

Thus, [A⁻] = 0,095M

That means you need <em>acetic acid 0,055M</em> and <em>acetate 0,095M</em> to obtain the buffer you need.

i hope it helps!

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mr_godi [17]

Answer:

None of the above could take place at the anode.

Explanation:

In a cell, a redox reaction takes place, so one substance must reduce (gain electrons), and others must oxidize (lose electrons). At the anode, the substance oxidizes, and at the cathode the substance reduces.

Thus, we need to find what transformation oxidation is happening. To this, let's calculate the oxidation number (nox) of the atoms. If it's increasing, and oxidation is happening, if it's decreasing, a reduction is happening.

O₂ to H₂O:

O2 is a simple substance, so it has nox = 0. In a compound, O has nox -2 and H +1, so the nox of O is decreasing.

Cr₂O₇⁻² → Cr⁺²:

O has nox -2, so let's call the nox of Cr as x:

2x +7*(-2) = -2

2x -14 = -2

x = +6

And Cr⁺² has nox +2, so it's reducing.

F₂ to F⁻:

F₂ is a simple substance, so F has nox 0, and F⁻ has nox -1, then it's reducing.

HAsO₂ to As:

H has nox +1, and O has nox -2, so calling x the nox of As:

+1 + x + 2*(-2) = 0

1 + x - 4 = 0

x = +3

And As is a simple substance, that has nox 0, the it's reducing.

Thus, none of them is oxidizing, and none of them could take place at the anode.

6 0
3 years ago
The positive sign of the energy difference in a chemical reaction would indicate that ..........
trasher [3.6K]

Answer:

B) the chemicals are gaining energy from the surroundings.

Explanation:

The positive sign of the energy difference in a chemical reaction would indicate that the chemicals are gaining energy from the surroundings. This is what happens in an endothermic reaction.

In an endothermic reaction, heat is absorbed from the surroundings hence the surrounding becomes colder at the end of the changes.

  • Here the energy change is assigned a positive value.
  • This is because the heat energy level of the final state is higher than that of the initial state.
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3 0
3 years ago
if the volume of a gas contracted from 648 mL to 0.15L, what was its final pressure if it started at a pressure of 485 kpa
bija089 [108]

Answer:

2100 kPa

Explanation:

The temperature is constant, so the only variables are pressure and volume.

We can use Boyle’s Law.

p₁V₁ = p₂V₂     Divide both sides of the equation by V₂

p₂ = p₁ × V₁/V₂  

p₁ = 485 kPa; V₁ =              648 mL  

p₂ = ?;            V₂ = 0.15 L = 150 mL      Calculate p₂

p₂ = 485 × 648/150

p₂ = 2100 kPa

4 0
3 years ago
If the hydrogen ion concentration, [H+], in a solution is 4.59 x 10-6 M, what is [OH-]?
atroni [7]

Answer:

2.18x10^-9 M

Explanation:

From the question given,

Hydrogen ion concentration, [H+] = 4.59x10^-6 M

Hydroxide ion, [OH-] =?

The hydroxide ion concentration, [OH-] in the solution can be obtained as follow:

[H+] x [OH-] = 1x10^-14

4.59x10^-6 x [OH-] = 1x10^-14

Divide both side by 4.59x10^-6

[OH-] = 1x10^-14 / 4.59x10^-6

[OH-] = 2.18x10^-9 M

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