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nasty-shy [4]
3 years ago
5

A chemist must prepare 800ml of potassium hydroxide solution with a pH 13 of at 25. He will do this in three steps:

Chemistry
1 answer:
Naily [24]3 years ago
8 0

Answer:

4.48 grams of potassium hydroxide that the chemist must be weighing out.

Explanation:

The pH of the KOH solution = 13

pH + pOH = 14

pOH = 14 - pH = 14 - 13 = 1

pOH=-\log[OH^-]

1=-\log[OH^-]

[OH^-]=0.1 M

KOH(aq)\rightarrow K^+(aq)+OH^-(aq)

1 mole of hydroxide ions are obtained from 1 mole of KOH. Then 0.1 mole of hydroxide ions will be obtained from :

\frac{1}{1}\times 0.1 M=0.1 M of KOH

[Molarity]=\frac{\text{Moles of solute}}{\text{Volume of solution(L)}}

Volume of KOH solution = 800 mL = 0.800 L ( 1 mL = 0.001 L)

0.1 M=\frac{\text{Moles of KOH}}{0.800 L}

Moles of KOH = 0.1 M × 0.800 L = 0.08 mol

Mass of 0.08 moles of KOH :

0.08 mol × 56 g/mol = 4.48 g

4.48 grams of potassium hydroxide that the chemist must be weighing out.

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The half reactions follows:

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To calculate the E^o_{cell} of the reaction, we use the equation:

E^o_{cell}=E^o_{cathode}-E^o_{anode}

Putting values in above equation, we get:

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