Answer:
(A) 0.129 M
(B) 0.237 M
Explanation:
(A) The reaction between potassium hydrogen phthalate and barium hydroxide is:
- 2HA + Ba(OH)₂ → BaA₂ + 2H₂O
Where A⁻ is the respective anion of the monoprotic acid (KC₈H₄O₄⁻).
We <u>convert mass of phthalate to moles</u>, using its molar mass:
- 0.978 g ÷ 156 g/mol = 9.27x10⁻³ mol = 9.27 mmol
Now we <u>convert mmol of HA to mmol of Ba(OH)₂</u>:
- 9.27 mmol HA *
= 6.64 mmol Ba(OH)₂
Finally we calculate the molarity of the Ba(OH)₂ solution:
- 6.64 mmol / 35.8 mL = 0.129 M
(B) The reaction between Ba(OH)₂ and HCl is:
- 2HCl + Ba(OH)₂ → BaCl₂ + 2H₂O
So<u> the moles of HCl that reacted </u>are:
- 17.1 mL * 0.129 M *
= 4.41 mmol HCl
And the <u>molarity of the HCl solution is</u>:
- 4.41 mmol / 18.6 mL = 0.237 M
Moles of oxygen = mass/molar mass of O2 = 8/31.998 = 0.25 moles.
Number of particles = moles x 6.02 x 10^23 = 0.25 x 6.02 x 10^23 = 1.505 x 10^23 particles.
Hope this helps!
You are given the neutralization of acetic acid with sodium hydroxide. Also, you are given the k for acetic acid, which is 1.8 x 10⁻⁵. You are asked to find the<span> approximate value of the equilibrium constant, kn, for the neutralization. We will have a reaction of both acetic acid and sodium hydroxide.
CH</span>₃COOH + NaOH → CH₃COONa + H₂O
which comes from
CH₃COOH → CH₃COO⁻ + H⁺
H⁺ + OH⁻ → H₂O<span>
</span>The k for water is always 1.0 x 10¹⁴. The Ksp for the reaction will be
<span>
Ksp = [</span>CH₃COOH][H₂O]
Ksp = (1.8 x 10⁻⁵)(1.0 x 10¹⁴)
<span>Ksp = 1.8 x 10</span>⁹
Answer:
The value of entropy change for the process 
Explanation:
Mass of the ideal gas = 0.0027 kilo mol
Initial volume
= 4 L
Final volume
= 6 L
Gas constant for this ideal gas ( R ) = 
Where
= Universal gas constant = 8.314 
⇒ Gas constant R = 8.314 × 0.0027 = 0.0224 
Entropy change at constant temperature is given by,

Put all the values in above formula we get,
![dS = 0.0224 log _{e} [\frac{6}{4}]](https://tex.z-dn.net/?f=dS%20%3D%200.0224%20%20log%20_%7Be%7D%20%5B%5Cfrac%7B6%7D%7B4%7D%5D)
This is the value of entropy change for the process.